<span class="word">Optical <span class="word">Rotatory <span class="word">Dispersion <span class="word">of <span class="word">Poly(l-<span class="word"><span class="changedDisabled">Lactic <span class="word">

Poly(l-lactic acid) or poly(l-lactide) (PLLA) is an optically active polymer derived from renewable sources and fully biodegradable. It is known that PLLA assumes a left-handed helix in the solid state and also in solution it still keeps a certain degree of helical structure. Here we examine the Optical Rotatory Dispersion (ORD) behavior of two grades of PLLA (medium molecular weight and hexadecyl-terminated or a high molecular weight for 3D printing) in 13 different solvents and through the Moffitt-Yang equation of the ORD data. Furthermore, the ORD data of PLLA in additional 6 solvents were taken from literature and analyzed with the Moffitt-Yang approach. The results suggest that also in solution PLLA maintain the left-handed helix and the most structurizing and helicogenic solvents for PLLA are ethyl acetate, acetonitrile, and certain chlorinated solvents. The equilibrium association constant (K) and other thermodynamic parameters (ΔG°, ΔH° and ΔS°) between PLLA and polyphenylacetylene (PPA another helical polymer in the solid state and in solution) were determined in trichloromethane, dichloromethane and tetrahydrofuran. The K values found suggest a strong helix-helix interaction between the two polymers. The ORD analysis of the PLLA-PPA solutions show evidences of the extrinsic Cotton effect and confirming the chiral helicity induction between the two polymers with 1:1 complex formation.