Genesis of an Inorganic CO2 Gas Reservoir in the Dehui–Wangfu Fault Depression, Songliao Basin, China

This study systematically examines the origins and formation mechanisms of inorganic CO2 gas reservoirs located within the Dehui–Wangfu Fault in the southeastern uplift region of the Songliao Basin. The research aims to clarify the primary sources of inorganic CO2, along with its migration and accumulation processes. The identification of the Wanjinta gas reservoir within the Dehui–Wangfu Fault Zone, abundant in inorganic CO2, has sparked significant interest in the pivotal roles of volcanism and tectonic activity in gas generation and concentration. To analyze the release characteristics of CO2, this study conducted degassing experiments on volcanic and volcaniclastic rock samples from various boreholes within the fault trap. It evaluated CO2 release behaviors and controlling factors across varying temperatures (150 °C to 600 °C) and particle sizes (20, 40, and 100 µm). The findings indicated a negative correlation between CO2 release and particle size, with a notable transition at 300 °C—marking this temperature as critical for the release of adsorbed and lattice gases. Moreover, volcaniclastic rocks exhibited higher CO2 release compared to volcanic rocks, attributable to their larger specific surface area and higher porosity. At 600 °C, the decomposition of the rock crystal structure results in substantial gas escape. These observations suggest that the inorganic CO2 in this area derives not only from mantle sources but is also influenced by crustal components. Elevated temperatures prompted by tectonic activity and magmatic intrusion facilitated the degassing of the surrounding rocks, allowing released CO2 to migrate upwards through the fracture system and accumulate in the shallow crust, ultimately forming a gas reservoir. This study enhances the understanding of volcanic rock’s roles in inorganic CO2 gas generation and migration, highlighting the fracture system’s critical controlling influence on gas transport and aggregation. The findings indicate that inorganic CO2 gas reservoirs in the Dehui–Wangfu Fault Zone primarily originate from mantle sources with a mixture of crustal gases. This discovery offers new theoretical insights and practical guidance for the exploration and development of gas reservoirs in the Songliao Basin and similar regions.