EVA and SEBS-MA copolymers incorporated silicone rubber/SEBS blends: improvement of mechanical and thermal properties

AbstractEnhancing the mechanical and thermal properties of Silicone rubber (SR)/SEBS blends using various compatibilizers opens the opportunity for such new blends to meet the market desire. For this purpose, blends with a 1:1 ratio of SR and SEBS are prepared with different amounts of EVA or SEBS-MA copolymers as compatibilizer. Mechanical properties of the blend are enhanced by adding EVA and SEBS-MA. Addition of 6 phr EVA profoundly improves the tensile strength from 7.70 to 10.06 MPa. Thermogravimetric analysis reveals that the presence of compatibilizer can improve the thermal stability of the blend, especially its initial degradation temperature (T5%). T5% of the blend increases from 376 to 390 °C when comprising 6 phr SEBS-MA. Morphology of the blends is investigated using SEM and AFM. Results of the relaxation modulus curves obtained by rubber process analyzer (RPA) demonstrate that the amount of relaxation in the uncured blends is higher than the cured ones. A comparison of the relaxation of the blends indicates that the relaxation modulus of the SEBS-MA compatibilized blends is enhanced more than other blends after curing. Further investigations indicate that the compatibilized blends exhibit higher tear energy and lower compression set.