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2.2 Transfer Hydrogenation of Ketones to Alcohols
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AbstractTransfer hydrogenation offers an alternative to hydrogenation using gaseous hydrogen, as well as a practical synthetic approach to enantiopure compounds. Alcohols, formic acid, and formate salts are often used as safe and nontoxic hydrogen sources in transition-metal catalyzed transfer hydrogenation systems. This chapter highlights effective transfer hydrogenation and asymmetric transfer hydrogenation of ketones catalyzed by transition-metal complexes. The reactions described in this section are classified according to the reducing agents employed and the type of ketone substrate.
Georg Thieme Verlag KG
Title: 2.2 Transfer Hydrogenation of Ketones to Alcohols
Description:
AbstractTransfer hydrogenation offers an alternative to hydrogenation using gaseous hydrogen, as well as a practical synthetic approach to enantiopure compounds.
Alcohols, formic acid, and formate salts are often used as safe and nontoxic hydrogen sources in transition-metal catalyzed transfer hydrogenation systems.
This chapter highlights effective transfer hydrogenation and asymmetric transfer hydrogenation of ketones catalyzed by transition-metal complexes.
The reactions described in this section are classified according to the reducing agents employed and the type of ketone substrate.
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