Redox processes of slightly-carbon-rich rocky planets

Whether a planet's volcanic gas is oxidising or reducing is inherited from redox conditions in the planet's mantle. It is often presumed that reactions between iron species control mantle oxygen fugacity. However, iron alone need not be the sole dictator of how oxidising the interior of a planet is. Carbon is a powerful redox element, with great potential to feed back upon the mantle redox state as it melts. Despite Earth being carbon-poor, it has been proposed that the oxygen fugacity of Earth's upper mantle is in part controlled by carbon (Holloway et al., 1992; Stagno et al., 2013); a slightly-higher volatile endowment could make carbon-powered geochemistry inescapable. Indeed, a number of known rocky exoplanets are predicted to have formed with carbon contents greater than Earth (Bergin et al., 2023). We offer a framework for how carbon is transported from solid planetary interior to atmosphere, tracking redox couplings between carbon and iron. We also incorporate a coupled 1D energy- and mass-balance model to provide first-order predictions of the rate of volcanism. We show that carbon-iron redox coupling would maintain interior oxygen fugacity in a narrow range: more reducing than Earth magma, but not reducing enough to prevent CO2 outgassing entirely.Bergin, E. A., Kempton, E. M.-R., Hirschmann, M., Bastelberger, S. T., Teal, D. J., Blake, G. A., Ciesla, F. J., & Li, J. (2023). Exoplanet Volatile Carbon Content as a Natural Pathway for Haze Formation. The Astrophysical Journal, 949, L17. Holloway, J. R., Pan, V., & Gudmundsson, G. (1992). High-pressure fluid-absent melting experiments in the presence of graphite: Oxygen fugacity, ferric/ferrous ratio and dissolved CO2. European Journal of Mineralogy, 4(1), 105–114. Stagno, V., Ojwang, D. O., McCammon, C. A., & Frost, D. J. (2013). The oxidation state of the mantle and the extraction of carbon from Earth’s interior. Nature, 493(7430).