Search engine for discovering works of Art, research articles, and books related to Art and Culture
Javascript must be enabled to continue!
Chlorocuprate(II) and Chlorocobaltate(II) Salts of the Aminodiphenyl-phosphonitrileaminodiphenylphosphonium Ion
View through CrossRef
Two new compounds [NH2(C6H5)2PNP(C6H5)2NH2]2[CoCl4] and [NH2(C6H5)2PNP(C6H5)2NH2][CoCl4]CH2Cl2 have been isolated, and characterized by spectrometry, as examples of the general series of quaternary amine transition metal chloride salts. Three other compounds containing the same cations, with empirical formulae, CuP2N3C25H32OCl3 (1), CuP2N3C24H28Cl3 (2), and Cu3P4N6C50H64O2Cl8 (3) have been isolated and studied by spectrometry. The formulae [NH2(C6H5)2PNP(C6H5)2NH2]2[Cu2Cl6] and [NH2(C6H5)2PNP(C6H5)2NH2]2[Cu2Cl6]. 2CH3OH are proposed for (2) and (1) by comparison with the cobalt compounds, and interpretation of the electronic structure. These compounds were produced during attempts to synthesize mixed ring compounds of (PN) and (SN) units.
Title: Chlorocuprate(II) and Chlorocobaltate(II) Salts of the Aminodiphenyl-phosphonitrileaminodiphenylphosphonium Ion
Description:
Two new compounds [NH2(C6H5)2PNP(C6H5)2NH2]2[CoCl4] and [NH2(C6H5)2PNP(C6H5)2NH2][CoCl4]CH2Cl2 have been isolated, and characterized by spectrometry, as examples of the general series of quaternary amine transition metal chloride salts.
Three other compounds containing the same cations, with empirical formulae, CuP2N3C25H32OCl3 (1), CuP2N3C24H28Cl3 (2), and Cu3P4N6C50H64O2Cl8 (3) have been isolated and studied by spectrometry.
The formulae [NH2(C6H5)2PNP(C6H5)2NH2]2[Cu2Cl6] and [NH2(C6H5)2PNP(C6H5)2NH2]2[Cu2Cl6].
2CH3OH are proposed for (2) and (1) by comparison with the cobalt compounds, and interpretation of the electronic structure.
These compounds were produced during attempts to synthesize mixed ring compounds of (PN) and (SN) units.
Related Results
Solid‐State Ion Exchange in Zeolites
Solid‐State Ion Exchange in Zeolites
AbstractThe sections in this article areIntroductionComparison of Conventional and Solid‐State Ion ExchangeExperimental Procedure for Solid‐State Ion Exchange in ZeolitesMethods of...
THE BIOLOGICAL SIGNIFICANCE OF CHEMICAL DIFFERENCES IN BILE SALTS
THE BIOLOGICAL SIGNIFICANCE OF CHEMICAL DIFFERENCES IN BILE SALTS
Summary1. The chemical nature of the bile salts is a character that must be under the control of several genes and is also affected by intestinal micro‐organisms and perhaps again ...
Exchanges of salts and volatiles in Europa’s hydrosphere
Exchanges of salts and volatiles in Europa’s hydrosphere
Ocean worlds have become a major focus of interest in exobiology and planetary science due to their internal structure and dynamics [1]. Among them, Europa is one of the most promi...
Linear ion traps in mass spectrometry
Linear ion traps in mass spectrometry
Abstract
I.
Introduction
000
II.
Linear Multipoles
000
A. Multipole Fields
000
1. Multipole Potentials
000
2. Ion Motion in 2D Multipole Fields
000...
Isolation, characterization and semi-synthesis of natural products dimeric amide alkaloids
Isolation, characterization and semi-synthesis of natural products dimeric amide alkaloids
Isolation, characterization of natural products dimeric amide alkaloids from roots of the Piper chaba Hunter. The synthesis of these products using intermolecular [4+2] cycloaddit...
Survey on the "plant salts" production and consumption in the west of Ivory Coast
Survey on the "plant salts" production and consumption in the west of Ivory Coast
A field survey was carried out to increase knowledge on salts produced from plants in the west of Ivory Coast. This work intends to serve as a basis for a real promotion of "plant ...
Simulation of unidirectional ion ejection in linear ion traps with asymmetric radiofrequency voltage
Simulation of unidirectional ion ejection in linear ion traps with asymmetric radiofrequency voltage
RationaleLinear ion traps with simplified structure have been widely used in miniaturized mass spectrometers. However, linear ion traps usually have low ion detection efficiency wh...
Ion Exchangers
Ion Exchangers
AbstractThe article contains sections titled:1.Introduction2.Structures of Ion‐Exchange Resins2.1.Polymer Matrices2.2.Functional Groups2.2.1.Cation‐Exchange Resins2.2.2.Anion‐Excha...