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Structure of Organoantimony Compounds [C5H4Mn(CO)3]Sb, (4-Me2NC6H4)3SbI2, Ph3Sb[OC(O)C6H3(NO2)2-3,5]2, (3-MeC6H4)3Sb[OC(O)C6H3(NO2)2-3,5]2xPhH, and (3-FC6H4)3Sb[OC(O)C6H3(NO2)2-3,5]2xPhH
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The structure of five organoantimony compounds [C5H4Mn(CO)3]Sb (1), (4-Me2NC6H4)3SbI2 (2), Ph3Sb[OC(O)C6H3(NO2)2-3,5]2 (3), (3-MeC6H4)3Sb[OC(O)C6H3(NO2)2-3,5]2PhH (4), and (3-FC6H4)3Sb[OC(O)C6H3(NO2)2-3,5]2PhH (5) was determined by X-ray diffraction analysis. X-ray diffraction of the compounds was carried out on an automatic four-circle diffractometer D8 Quest Bruker (МоКα, λ = 0.71073 Å, 293 К. [C5H4Mn(CO)3]Sb (1), crystal size 0.53×0.4×0.22 mm, R-3, a = 19.221(6), b = 19.221(6), c = 11.935(4) Å, = 90.00, β = 90.00, = 120.00 deg., V = 3818.6(17) Å3, Z = 2, R1 = 0.0484, wR2 = 0.0900. (4-Me2NC6H4)3SbI2 (2), crystal size 0.26 × 0.19 × 0.16 mm, Ia-3, a = 22.238(13), b = 22.238(13), c = 22.238(13) Å, = 90.00, β = 90.00, = 90.00 deg., V = 10997(19) Å3, Z = 48, R1 = 0.0372, wR2 = 0.0855. Ph3Sb[OC(O)C6H3(NO2)2-3,5]2 (3), crystal size 0.39×0.29×0.19 mm, P-1, a = 11.985(8), b = 12.186(7), c = 14.292(10) Å, = 72.30(3), β = 69.64(3), = 61.79(3) deg., V = 1699.8(19) Å3, Z = 2, R1 = 0.0388, wR2 = 0.1246. (3-MeC6H4)3Sb[OC(O)C6H3(NO2)2-3,5]2PhH (4), crystal size 0.2 × 0.17 × 0.07 mm, P-1, a = 12.654(8), b = 13.217(9), c = 14.672(13) Å, = 64.42(3), β = 79.73(3), = 65.66(2) deg., V = 2017(3) Å3, Z = 2, R1 = 0.0350, wR2 = 0.0870. (3-FC6H4)3Sb[OC(O)C6H3(NO2)2-3,5]2PhH (5), crystal size 0.55×0.4×0.19 мм, P-1, a = 12.34(3), b = 12.95(2), c = 14.41(2) Å, = 81.73(6), β = 66.94(10), = 66.31(7) deg., V = 1940(6) Å3, Z = 2, R1 = 0.0721, wR2 = 0.1558.
FSAEIHE South Ural State University (National Research University)
Title: Structure of Organoantimony Compounds [C5H4Mn(CO)3]Sb, (4-Me2NC6H4)3SbI2, Ph3Sb[OC(O)C6H3(NO2)2-3,5]2, (3-MeC6H4)3Sb[OC(O)C6H3(NO2)2-3,5]2xPhH, and (3-FC6H4)3Sb[OC(O)C6H3(NO2)2-3,5]2xPhH
Description:
The structure of five organoantimony compounds [C5H4Mn(CO)3]Sb (1), (4-Me2NC6H4)3SbI2 (2), Ph3Sb[OC(O)C6H3(NO2)2-3,5]2 (3), (3-MeC6H4)3Sb[OC(O)C6H3(NO2)2-3,5]2PhH (4), and (3-FC6H4)3Sb[OC(O)C6H3(NO2)2-3,5]2PhH (5) was determined by X-ray diffraction analysis.
X-ray diffraction of the compounds was carried out on an automatic four-circle diffractometer D8 Quest Bruker (МоКα, λ = 0.
71073 Å, 293 К.
[C5H4Mn(CO)3]Sb (1), crystal size 0.
53×0.
4×0.
22 mm, R-3, a = 19.
221(6), b = 19.
221(6), c = 11.
935(4) Å, = 90.
00, β = 90.
00, = 120.
00 deg.
, V = 3818.
6(17) Å3, Z = 2, R1 = 0.
0484, wR2 = 0.
0900.
(4-Me2NC6H4)3SbI2 (2), crystal size 0.
26 × 0.
19 × 0.
16 mm, Ia-3, a = 22.
238(13), b = 22.
238(13), c = 22.
238(13) Å, = 90.
00, β = 90.
00, = 90.
00 deg.
, V = 10997(19) Å3, Z = 48, R1 = 0.
0372, wR2 = 0.
0855.
Ph3Sb[OC(O)C6H3(NO2)2-3,5]2 (3), crystal size 0.
39×0.
29×0.
19 mm, P-1, a = 11.
985(8), b = 12.
186(7), c = 14.
292(10) Å, = 72.
30(3), β = 69.
64(3), = 61.
79(3) deg.
, V = 1699.
8(19) Å3, Z = 2, R1 = 0.
0388, wR2 = 0.
1246.
(3-MeC6H4)3Sb[OC(O)C6H3(NO2)2-3,5]2PhH (4), crystal size 0.
2 × 0.
17 × 0.
07 mm, P-1, a = 12.
654(8), b = 13.
217(9), c = 14.
672(13) Å, = 64.
42(3), β = 79.
73(3), = 65.
66(2) deg.
, V = 2017(3) Å3, Z = 2, R1 = 0.
0350, wR2 = 0.
0870.
(3-FC6H4)3Sb[OC(O)C6H3(NO2)2-3,5]2PhH (5), crystal size 0.
55×0.
4×0.
19 мм, P-1, a = 12.
34(3), b = 12.
95(2), c = 14.
41(2) Å, = 81.
73(6), β = 66.
94(10), = 66.
31(7) deg.
, V = 1940(6) Å3, Z = 2, R1 = 0.
0721, wR2 = 0.
1558.
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