Search engine for discovering works of Art, research articles, and books related to Art and Culture
Javascript must be enabled to continue!
Structure of Organoantimony Compounds [C5H4Mn(CO)3]Sb, (4-Me2NC6H4)3SbI2, Ph3Sb[OC(O)C6H3(NO2)2-3,5]2, (3-MeC6H4)3Sb[OC(O)C6H3(NO2)2-3,5]2xPhH, and (3-FC6H4)3Sb[OC(O)C6H3(NO2)2-3,5]2xPhH
View through CrossRef
The structure of five organoantimony compounds [C5H4Mn(CO)3]Sb (1), (4-Me2NC6H4)3SbI2 (2), Ph3Sb[OC(O)C6H3(NO2)2-3,5]2 (3), (3-MeC6H4)3Sb[OC(O)C6H3(NO2)2-3,5]2PhH (4), and (3-FC6H4)3Sb[OC(O)C6H3(NO2)2-3,5]2PhH (5) was determined by X-ray diffraction analysis. X-ray diffraction of the compounds was carried out on an automatic four-circle diffractometer D8 Quest Bruker (МоКα, λ = 0.71073 Å, 293 К. [C5H4Mn(CO)3]Sb (1), crystal size 0.53×0.4×0.22 mm, R-3, a = 19.221(6), b = 19.221(6), c = 11.935(4) Å, = 90.00, β = 90.00, = 120.00 deg., V = 3818.6(17) Å3, Z = 2, R1 = 0.0484, wR2 = 0.0900. (4-Me2NC6H4)3SbI2 (2), crystal size 0.26 × 0.19 × 0.16 mm, Ia-3, a = 22.238(13), b = 22.238(13), c = 22.238(13) Å, = 90.00, β = 90.00, = 90.00 deg., V = 10997(19) Å3, Z = 48, R1 = 0.0372, wR2 = 0.0855. Ph3Sb[OC(O)C6H3(NO2)2-3,5]2 (3), crystal size 0.39×0.29×0.19 mm, P-1, a = 11.985(8), b = 12.186(7), c = 14.292(10) Å, = 72.30(3), β = 69.64(3), = 61.79(3) deg., V = 1699.8(19) Å3, Z = 2, R1 = 0.0388, wR2 = 0.1246. (3-MeC6H4)3Sb[OC(O)C6H3(NO2)2-3,5]2PhH (4), crystal size 0.2 × 0.17 × 0.07 mm, P-1, a = 12.654(8), b = 13.217(9), c = 14.672(13) Å, = 64.42(3), β = 79.73(3), = 65.66(2) deg., V = 2017(3) Å3, Z = 2, R1 = 0.0350, wR2 = 0.0870. (3-FC6H4)3Sb[OC(O)C6H3(NO2)2-3,5]2PhH (5), crystal size 0.55×0.4×0.19 мм, P-1, a = 12.34(3), b = 12.95(2), c = 14.41(2) Å, = 81.73(6), β = 66.94(10), = 66.31(7) deg., V = 1940(6) Å3, Z = 2, R1 = 0.0721, wR2 = 0.1558.
FSAEIHE South Ural State University (National Research University)
Title: Structure of Organoantimony Compounds [C5H4Mn(CO)3]Sb, (4-Me2NC6H4)3SbI2, Ph3Sb[OC(O)C6H3(NO2)2-3,5]2, (3-MeC6H4)3Sb[OC(O)C6H3(NO2)2-3,5]2xPhH, and (3-FC6H4)3Sb[OC(O)C6H3(NO2)2-3,5]2xPhH
Description:
The structure of five organoantimony compounds [C5H4Mn(CO)3]Sb (1), (4-Me2NC6H4)3SbI2 (2), Ph3Sb[OC(O)C6H3(NO2)2-3,5]2 (3), (3-MeC6H4)3Sb[OC(O)C6H3(NO2)2-3,5]2PhH (4), and (3-FC6H4)3Sb[OC(O)C6H3(NO2)2-3,5]2PhH (5) was determined by X-ray diffraction analysis.
X-ray diffraction of the compounds was carried out on an automatic four-circle diffractometer D8 Quest Bruker (МоКα, λ = 0.
71073 Å, 293 К.
[C5H4Mn(CO)3]Sb (1), crystal size 0.
53×0.
4×0.
22 mm, R-3, a = 19.
221(6), b = 19.
221(6), c = 11.
935(4) Å, = 90.
00, β = 90.
00, = 120.
00 deg.
, V = 3818.
6(17) Å3, Z = 2, R1 = 0.
0484, wR2 = 0.
0900.
(4-Me2NC6H4)3SbI2 (2), crystal size 0.
26 × 0.
19 × 0.
16 mm, Ia-3, a = 22.
238(13), b = 22.
238(13), c = 22.
238(13) Å, = 90.
00, β = 90.
00, = 90.
00 deg.
, V = 10997(19) Å3, Z = 48, R1 = 0.
0372, wR2 = 0.
0855.
Ph3Sb[OC(O)C6H3(NO2)2-3,5]2 (3), crystal size 0.
39×0.
29×0.
19 mm, P-1, a = 11.
985(8), b = 12.
186(7), c = 14.
292(10) Å, = 72.
30(3), β = 69.
64(3), = 61.
79(3) deg.
, V = 1699.
8(19) Å3, Z = 2, R1 = 0.
0388, wR2 = 0.
1246.
(3-MeC6H4)3Sb[OC(O)C6H3(NO2)2-3,5]2PhH (4), crystal size 0.
2 × 0.
17 × 0.
07 mm, P-1, a = 12.
654(8), b = 13.
217(9), c = 14.
672(13) Å, = 64.
42(3), β = 79.
73(3), = 65.
66(2) deg.
, V = 2017(3) Å3, Z = 2, R1 = 0.
0350, wR2 = 0.
0870.
(3-FC6H4)3Sb[OC(O)C6H3(NO2)2-3,5]2PhH (5), crystal size 0.
55×0.
4×0.
19 мм, P-1, a = 12.
34(3), b = 12.
95(2), c = 14.
41(2) Å, = 81.
73(6), β = 66.
94(10), = 66.
31(7) deg.
, V = 1940(6) Å3, Z = 2, R1 = 0.
0721, wR2 = 0.
1558.
Related Results
Oxidation of triaryl antimony Ar3Sb [Ar = 4-FC6H4, (4-F3C)C6H4, (2-MeO)C6H4, 4-BrC6H4, 3-MeC6H4, 4-MeC6H4, (4-Me2N)C6H4, (2-MeO)(5-Br)C6H3] with benzoyl peroxide
Oxidation of triaryl antimony Ar3Sb [Ar = 4-FC6H4, (4-F3C)C6H4, (2-MeO)C6H4, 4-BrC6H4, 3-MeC6H4, 4-MeC6H4, (4-Me2N)C6H4, (2-MeO)(5-Br)C6H3] with benzoyl peroxide
Oxidation of triarylantimony Ar3Sb with benzoyl peroxide in benzene gave the correspond-ing dibenzoates Ar3Sb[OC(O)Ph]2 [Ar = 4-FC6H4 (1), (4-F3C)C6H4 (2), (2-MeO)C6H4 (3), 4-BrC6H...
Amine Oxidation Catalyzed by NO2
Amine Oxidation Catalyzed by NO2
Amine oxidation is a major risk in the deployment of amine scrubbing for CO2 capture from post-combustion flue gas. Oxidation probably occurs by dissolved oxygen at elevated temper...
A research product for tropospheric NO2 columns fromGeostationary Environment Monitoring Spectrometerbased on Peking University OMI NO2 algorithm
A research product for tropospheric NO2 columns fromGeostationary Environment Monitoring Spectrometerbased on Peking University OMI NO2 algorithm
Tropospheric vertical column densities (VCDs) of nitrogen dioxide (NO2) retrieved from sun-synchronous satellite instruments have provided abundant NO2 data for environmental studi...
Structural features of triarylantimony derivatives Ph3Sb(OC6H3F2-2,4)2 and Ar3Sb[OC(O)R]2 [Ar = Ph, R = CHF2, Ar = 2-MeOC6H4, R = C6H3F2-2,5, Ar = 3-CF3C6H4, R = Ph, Ar = (2-MeO)(5-Br)C6H3, R = C6H3F2-2,3]
Structural features of triarylantimony derivatives Ph3Sb(OC6H3F2-2,4)2 and Ar3Sb[OC(O)R]2 [Ar = Ph, R = CHF2, Ar = 2-MeOC6H4, R = C6H3F2-2,5, Ar = 3-CF3C6H4, R = Ph, Ar = (2-MeO)(5-Br)C6H3, R = C6H3F2-2,3]
Triarylantimony derivatives Ph3Sb(OC6H3F2-2,4)2 (1) and Ar3Sb[OC(O)R]2 [Ar = Ph, R = CHF2 (2), Ar = 2-MeOC6H4, R = C6H3F2-2,5 (3), Ar = 3-CF3C6H4, R = Ph (4), Ar = (2-MeO)(5-Br)C6H...
Analisis Kadar NO2 dalam Kangkung Air (Ipomoea aquatica Forsk) dan Kangkung Darat (Ipomoea reptans Poir) Asal Kelurahan Gambesi Kota Ternate
Analisis Kadar NO2 dalam Kangkung Air (Ipomoea aquatica Forsk) dan Kangkung Darat (Ipomoea reptans Poir) Asal Kelurahan Gambesi Kota Ternate
AbstrakTujuan penelitian ini untuk mengetahui kadar NO2 dalam kangkung air (Ipomoea aquatica Forsk) dan Kangkung Darat (Ipomoea reptans Poir) asal Kelurahan Gambesi, Kota Ternate. ...
Crystal structures of hydrazones, 2-(1,3-benzothiazolyl)-NH—N=CH—Ar, prepared from arenealdehydes and 2-hydrazinyl-1,3-benzothiazole
Crystal structures of hydrazones, 2-(1,3-benzothiazolyl)-NH—N=CH—Ar, prepared from arenealdehydes and 2-hydrazinyl-1,3-benzothiazole
Abstract
Structures of hydrazones, [1: 2-(1,3-benzothiazolyl)-NH—N=CH—C6H3—XY], prepared from arenecarbäaldehydes and 2-hydrazinyl-1,3-benzothiazole, are reported. C...
Space-borne Air Quality Monitoring of Nitrogen dioxide (NO2) over Karachi and Lahore using Remote Sensing Tools
Space-borne Air Quality Monitoring of Nitrogen dioxide (NO2) over Karachi and Lahore using Remote Sensing Tools
In this study, we used Sentinel-5P TROPOMI satellite data to examine the NO2 and gas concentrations in the cities of Lahore and Karachi, Pakistan, and to use environmental valuatio...