Search engine for discovering works of Art, research articles, and books related to Art and Culture
Javascript must be enabled to continue!
Abundant Manganese Complex-Anchored BiOI Hybrid Photocatalyst for Visible Light-Driven CO2 Reduction
View through CrossRef
An abundant manganese complex-anchored BiOI hybrid system for CO2 photocatalytic conversion was constructed. Layered BiOI and tricarbonyl Mn bipyridyl complex with carboxyl acid groups were connected with covalent bonds and used as visible light antenna and CO2 reduction reaction centers, respectively. The covalent connection of this hybrid system benefits the transfer of electrons from the semiconductor to the Mn complex. The anchoring group (carboxyl) is the key to CO2 reduction for the direct coupling of the two units, facilitating the transfer of electrons from BiOI to the manganese complexes. The photocatalytic properties and stability of the tricarbonyl Mn–bipyridyl complex were significantly enhanced with the aid of anchored BiOI. A high turnover number ([Formula: see text]) of HCOO− formation from CO2 could be achieved using this hybrid system under visible light irradiation.
Title: Abundant Manganese Complex-Anchored BiOI Hybrid Photocatalyst for Visible Light-Driven CO2 Reduction
Description:
An abundant manganese complex-anchored BiOI hybrid system for CO2 photocatalytic conversion was constructed.
Layered BiOI and tricarbonyl Mn bipyridyl complex with carboxyl acid groups were connected with covalent bonds and used as visible light antenna and CO2 reduction reaction centers, respectively.
The covalent connection of this hybrid system benefits the transfer of electrons from the semiconductor to the Mn complex.
The anchoring group (carboxyl) is the key to CO2 reduction for the direct coupling of the two units, facilitating the transfer of electrons from BiOI to the manganese complexes.
The photocatalytic properties and stability of the tricarbonyl Mn–bipyridyl complex were significantly enhanced with the aid of anchored BiOI.
A high turnover number ([Formula: see text]) of HCOO− formation from CO2 could be achieved using this hybrid system under visible light irradiation.
Related Results
A New Method for Calculating Manganese Content and Determining Appropriate Manganese Levels in Foods
A New Method for Calculating Manganese Content and Determining Appropriate Manganese Levels in Foods
Calculating the manganese content per 100 kcal, 100 g or 100 mL, or the reference amount customarily consumed (RACC) of food shows the manganese content of some foods inappropriate...
Solar fuels via two-step thermochemical redox cycles for power and fuel production
Solar fuels via two-step thermochemical redox cycles for power and fuel production
With the issue of the rise of anthropogenic CO2, global warming and rise of the primary energy demand, strong measures for the energy transition and the diversification with renewa...
Spontaneous Adsorption and Efficient Photodegradation of Indigo Carmine under Visible Light by Bismuth Oxyiodide Nanoparticles Fabricated Entirely at Room Temperature
Spontaneous Adsorption and Efficient Photodegradation of Indigo Carmine under Visible Light by Bismuth Oxyiodide Nanoparticles Fabricated Entirely at Room Temperature
Bismuth oxyiodide (BiOI) is a targeted material for its relative safety and photocatalytic activity under visible light. In this study, a successful simple and energy-saving route ...
The effect of manganese on virulence gene expression in streptococcus mutans
The effect of manganese on virulence gene expression in streptococcus mutans
Streptococcus mutans was tested for its ability to grow in the absence or presence of various concentrations of manganese. The effect of manganese on the expression of virulence ge...
Rapid Large-scale Trapping of CO2 via Dissolution in US Natural CO2 Reservoirs
Rapid Large-scale Trapping of CO2 via Dissolution in US Natural CO2 Reservoirs
Naturally occurring CO2 reservoirs across the USA are critical natural analogues of long-term CO2 storage in the subsurface over geological timescales and provide valuable insights...
Engineered Oxygen Vacancies in NiCo2O4/BiOI Heterostructures for Enhanced Photocatalytic Pollutant Degradation
Engineered Oxygen Vacancies in NiCo2O4/BiOI Heterostructures for Enhanced Photocatalytic Pollutant Degradation
Abstract
To address the bottleneck issue of poor carrier separation and transfer efficiency in NiCo2O4 photocatalyst, a novel 1D/2D-rod on rose like NiCO2O4/BiOI nanohybrid...
Design And Operation Of The Levelland Unit CO2 Injection Facility
Design And Operation Of The Levelland Unit CO2 Injection Facility
Abstract
The Levelland CO2 Facility provides CO2 storageand handling capacity for the five CO2 injection pilots located in the Levelland Unit. Facilities pilots l...
An Emerging CO2 Storage Option: CO2 Storage and By-Product Oil Recovery from Shale Oil Formations
An Emerging CO2 Storage Option: CO2 Storage and By-Product Oil Recovery from Shale Oil Formations
Recent studies, sponsored by the United States Energy Association (USEA) and prepared by Advanced Resources International, have identified an emerging CO2 storage option – injectin...