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The Role of Free N‐Heterocyclic Carbene (NHC) in the Catalytic Dehydrogenation of Ammonia–Borane in the Nickel NHC System
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AbstractEnders' N‐heterocyclisches Carben (NHC) dehydriert den Ammoniak‐Boran‐Komplex mit einer vergleichsweise niedrigen Aktivierungsbarriere zu NH2BH2 und NHC‐(H)2. Ein Nickel‐NHC‐Katalysator im Reaktionsmedium zersetzt das gebildete NHC‐(H)2 in H2 und freies NHC, das wiederum Ammoniak‐Boran‐Komplex dehydrieren kann.magnified image
Title: The Role of Free N‐Heterocyclic Carbene (NHC) in the Catalytic Dehydrogenation of Ammonia–Borane in the Nickel NHC System
Description:
AbstractEnders' N‐heterocyclisches Carben (NHC) dehydriert den Ammoniak‐Boran‐Komplex mit einer vergleichsweise niedrigen Aktivierungsbarriere zu NH2BH2 und NHC‐(H)2.
Ein Nickel‐NHC‐Katalysator im Reaktionsmedium zersetzt das gebildete NHC‐(H)2 in H2 und freies NHC, das wiederum Ammoniak‐Boran‐Komplex dehydrieren kann.
magnified image.
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