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Collaborative Study of a Gas Chromatographic Method for Ronnel in Feeds

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Abstract A GLC method (flame ionization detector) for ronnel in cattle feeds at levels of 0.038, 0.041, and 0.055% was studied by 11 collaborators. The method involves extraction of ronnel by shaking with acetone followed by direct chromatographic measurement. The method is simple and rapid (no cleanup required), measures true ronnel, and is free from interferences present in the UV methods previously studied. Agreement between laboratories was satisfactory; coefficients of variation were 11.0, 12.0, and 7.2%. Ronnel recoveries were 81.1, 93.5, and 98.0%. Low recovery from the first sample may be due to ronnel hydrolysis or binding during storage (sample was 8 months old). The Associate Keferee recommends that the method be adopted as official first action.
Oxford University Press (OUP)
Title: Collaborative Study of a Gas Chromatographic Method for Ronnel in Feeds
Description:
Abstract A GLC method (flame ionization detector) for ronnel in cattle feeds at levels of 0.
038, 0.
041, and 0.
055% was studied by 11 collaborators.
The method involves extraction of ronnel by shaking with acetone followed by direct chromatographic measurement.
The method is simple and rapid (no cleanup required), measures true ronnel, and is free from interferences present in the UV methods previously studied.
Agreement between laboratories was satisfactory; coefficients of variation were 11.
0, 12.
0, and 7.
2%.
Ronnel recoveries were 81.
1, 93.
5, and 98.
0%.
Low recovery from the first sample may be due to ronnel hydrolysis or binding during storage (sample was 8 months old).
The Associate Keferee recommends that the method be adopted as official first action.

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