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The Polysiloxanes

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Polysiloxanes are the most studied inorganic and semi-inorganic polymers because of their many medical and commercial uses. The Si-O backbone endows polysiloxanes with intriguing properties: the strength of the Si-O bond imparts considerable thermal stability, and the nature of the bonding imparts low surface free energy. Prostheses, artificial organs, objects for facial reconstruction, vitreous substitutes in the eyes, and tubing take advantage of the stability and pliability of polysiloxanes. Artificial skin, contact lenses, and drug delivery systems utilize their high permeability. Such biomedical applications have led to biocompatibility studies on the interactions of polysiloxanes with proteins, and there has been interest in modifying these materials to improve their suitability for general biomedical application. Polysiloxanes examines novel aspects of polysiloxane science and engineering, including properties, work in progress, and important unsolved problems. The volume, with ten comprehensive chapters, examines the history, preparation and analysis, synthesis, characterization, and applications of these polymeric materials.
Title: The Polysiloxanes
Description:
Polysiloxanes are the most studied inorganic and semi-inorganic polymers because of their many medical and commercial uses.
The Si-O backbone endows polysiloxanes with intriguing properties: the strength of the Si-O bond imparts considerable thermal stability, and the nature of the bonding imparts low surface free energy.
Prostheses, artificial organs, objects for facial reconstruction, vitreous substitutes in the eyes, and tubing take advantage of the stability and pliability of polysiloxanes.
Artificial skin, contact lenses, and drug delivery systems utilize their high permeability.
Such biomedical applications have led to biocompatibility studies on the interactions of polysiloxanes with proteins, and there has been interest in modifying these materials to improve their suitability for general biomedical application.
Polysiloxanes examines novel aspects of polysiloxane science and engineering, including properties, work in progress, and important unsolved problems.
The volume, with ten comprehensive chapters, examines the history, preparation and analysis, synthesis, characterization, and applications of these polymeric materials.

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Applications
Applications
Numerous medical applications have been developed for siloxane polymers. Prostheses, artificial organs, objects for facial reconstruction, vitreous substitutes in the eyes, tubing ...
Surfaces
Surfaces
Because of the great importance of the surface properties of the polysiloxanes, this topic is treated separately in this chapter. Hydrophobic polysiloxanes having simple aliphatic ...
Introduction
Introduction
Polysiloxanes are unique among inorganic and semi-inorganic polymers; they are also the most studied and the most important with regard to commercial applications. Thus, it’s not s...
General Properties
General Properties
Many of the properties of the polysiloxanes have been tabulated in handbooks of polymer science and engineering. Recent work has included the stretching of polydimethylsiloxane (PD...
Types of Polysiloxanes
Types of Polysiloxanes
The polysiloxane of greatest commercial importance and scientific interest is poly(dimethylsiloxane) (PDMS), [Si(CH3)2 –O –]x, a member of the symmetrical dialkyl polysiloxanes, wi...
Synthesis of Linear Fullerene-Containing Polysiloxanes and Their Application to Capillary Gas Chromatography
Synthesis of Linear Fullerene-Containing Polysiloxanes and Their Application to Capillary Gas Chromatography
Abstract Fullerene-containing polysiloxanes were prepared by reacting [60]fullerene with azidoalkyl polysiloxanes directly, and characterized by FT-IR, UV-Vis, 1H-NM...
Nonconventional aggregation-induced emission polysiloxanes: topologies, characteristics and applications
Nonconventional aggregation-induced emission polysiloxanes: topologies, characteristics and applications
Nonconventional luminescent materials have been rising stars in organic luminophores due to their intrinsic characteristics, including water-solubility, biocompatibility and enviro...
Nonconventional aggregation‐induced emission polysiloxanes: Structures, characteristics, and applications
Nonconventional aggregation‐induced emission polysiloxanes: Structures, characteristics, and applications
Abstract Nonconventional luminescent materials have been rising stars in organic luminophores due to their intrinsic characteristics, including water‐solubility, ...

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