Asphaltene Thermodynamic Flocculation during Immiscible Nitrogen Gas Injection

SummaryGas-enhanced oil recovery is one of the most advantageous enhanced oil recovery methods. Nitrogen is one of the most investigated gases because of its beneficial properties. However, during its interaction with crude oil, nitrogen can induce asphaltene deposition, which may result in severe formation damage and pore plugging. Few works have investigated the impact of nitrogen on asphaltene instability. This research studied the immiscibility conditions for nitrogen in nanopores and the impact of nitrogen on asphaltene precipitations, which could lead to plugging pores and oil recovery reduction. A slimtube was used to determine the minimum miscibility pressure (MMP) of nitrogen to ensure that all the experiments would be carried out below the MMP. Then, filtration experiments were conducted using nanofilter membranes to highlight the impact of the asphaltene particles on the pores of the membranes. A special filtration vessel was designed and used to accommodate the filter paper membranes. Various factors were investigated, including nitrogen injection pressure, temperature, nitrogen mixing time, and pore size heterogeneity. Supercritical phase nitrogen was used during all filtration experiments. Visualization tests were implemented to observe the asphaltene precipitation and deposition mechanism over time. Increasing the nitrogen injection pressure resulted in an increase in the asphaltene weight percent in all experiments. Decreasing the pore size of the filter membranes resulted in an increase in the asphaltene weight percent. Greater asphaltene weight percents were observed with a longer nitrogen mixing time. Visualization tests revealed that asphaltene clusters started to form after 1 hour and fully deposited after 12 hours in the bottom of the test tubes. Chromatography analysis of the produced oil confirmed that there was a reduction in the heavy components and asphaltene weight percent. Microscopy and scanning electron microscopy (SEM) imaging of the filter paper membranes found that significant pore plugging resulted from asphaltene deposition and precipitation. This research investigated asphaltene precipitation and deposition during immiscible nitrogen injection to understand the main factors that impact the success of using such a technique in unconventional shale reservoirs.