The effects of hydrodynamic sorting on the Ti isotope composition of sediments

<p>Detrital sediments provide a useful tool to investigate the composition of the continental crust through time. Mass-dependent (“stable”) isotope variations in Archaean to present-day sediments (shales, diamictites) have recently received much attention and Ti, in particular, holds significant promise as a novel tracer of crustal composition [1, 2, 3]. This approach is based on i) the contrasting Ti isotope composition of mafic versus felsic rocks as a result of the removal of isotopically light oxides during igneous differentiation; and ii) the chemical behaviour of Ti, a refractory and biologically inert element that should not fractionate during weathering and sedimentation. Hence, current interpretations of the Ti isotope detrital sediment record rely heavily on the assumption that it reflects the integrated composition of the source(s), and thus provides a record of the proportion of felsic to mafic rocks in that source.</p><p>A potential caveat, however, is the hydrodynamic sorting of dense minerals in coarse, more proximal sediments [4]. This effect is well-known for zircon; coarser sediments tend to have higher Zr/Al<sub>2</sub>O<sub>3</sub> and a less radiogenic Hf isotope composition due to the concentration of zircon grains [e.g., 5, 6]. Shales form the complementary zircon-depleted reservoir characterised by lower Zr/Al<sub>2</sub>O<sub>3</sub> and a more radiogenic Hf isotope composition relative to the source. Common Ti-rich phases such as ilmenite and rutile are also resistant against physical and chemical weathering and could be concentrated together with zircon in coarse sediments.</p><p>We examined a suite of Eastern Mediterranean passive margin sediments with well-constrained provenance [7] and found that Ti indeed behaves like Zr. Fine-grained samples have lower TiO<sub>2</sub>/Al<sub>2</sub>O<sub>3</sub> compared to coarser, proximal deposits of identical provenance. The removal of Ti-rich phases with a light Ti isotope composition into coarse-grained sediments could thus bias the Ti isotope composition of shales towards isotopically heavier values. We will report on the δ<sup>49/47</sup>Ti isotope composition of these sediment samples, but a TiO<sub>2</sub>/Al<sub>2</sub>O<sub>3</sub> mass balance suggests that a bias of more than 0.05 ‰ in the δ<sup>49/47</sup>Ti of shales is possible. Understanding the consequences of hydrodynamic sorting for Ti isotopes in sediments is crucial for their use as a quantitative proxy of crustal composition and for reconciling the shale and diamictite Ti isotope records.</p><p>[1] Greber <em>et al.</em> (2017) <em>Science</em> <strong>357</strong> 1271-1274; [2] Deng <em>et al.</em> (2019) <em>PNAS</em> <strong>116-4</strong> 1132-1135; [3] Saji <em>et al.</em> (2019) <em>Goldschmidt abstract</em> <strong>2929</strong>; [4] Greber & Dauphas (2019) <em>GCA</em> <strong>255</strong> 247-264; [5] Patchett <em>et al.</em> (1984) <em>EPSL</em> <strong>69</strong> 365-378; [6] Carpentier <em>et al.</em> (2009) <em>EPSL</em> <strong>287</strong> 86-99; [7] Klaver <em>et al.</em> (2015) <em>GCA</em> <strong>153</strong> 149-168.</p>