Effect of Al2O3 on Crystallization, Microstructure, and Properties of Glass Ceramics Based on Lead Fuming Furnace-Slag

In the paper, glass ceramics used as architectural materials were prepared based on lead fuming furnace-slag (LFFS) by a synergistic sinter-crystallization method. The effects of Al2O3 addition on the crystallization phase, crystallization kinetics, and mechanical performance of glass ceramics were investigated. The results showed that the phases of the glass ceramics prepared were composed of gehlenite and wollastonite, and crystallization kinetics analysis showed that bulk crystallization dominated the overall crystallization process in the Al2O3 content range from 2% to 8%. The glass transition temperature and the crystallization peak temperature of the glass ceramics generally increased with the increase in the Al2O3 content. Additionally, the crystalline morphology gradually developed from sheet-like to spherical, while the number of pores increased and the bulk density gradually decreased. When the Al2O3 content was 2%, the bending strength of glass ceramics reached its maximum, 75.1 MPa, corresponding to a bulk density of 2.24 g·cm−3. Owing to the high strength and relatively low bulk density, the sintered glass ceramics appear promising for potential applications in lightweight construction tiles.