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CH Functionalization Reactions of Heterocycles via Carbene Transfer Reactions
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Abstract
Carbene transfer reactions of diazoalkanes are a powerful tool for the direct CH functionalization of heterocycles. Diazoalkanes have proven as excellent precursors to access free or metal‐bound carbene intermediates with molecular nitrogen as the sole by‐product. Herein, we describe carbene transfer reactions for the selective CH functionalization of heterocycles such as pyrrole, indole, or carbazole. Developments in metal‐catalyzed and light‐mediated approaches will be discussed in detail.
Title: CH Functionalization Reactions of Heterocycles via Carbene Transfer Reactions
Description:
Abstract
Carbene transfer reactions of diazoalkanes are a powerful tool for the direct CH functionalization of heterocycles.
Diazoalkanes have proven as excellent precursors to access free or metal‐bound carbene intermediates with molecular nitrogen as the sole by‐product.
Herein, we describe carbene transfer reactions for the selective CH functionalization of heterocycles such as pyrrole, indole, or carbazole.
Developments in metal‐catalyzed and light‐mediated approaches will be discussed in detail.
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