Immobilization of Molecular Catalysts

Title: Immobilization of Molecular Catalysts

Description:

Abstract The sections in this article are Introduction and Scope Metal Complex–Support Interaction Physically Immobilized (“Entrapped”) Metal Complexes Intrazeolite Assembly: Ship‐in‐a‐Bottle Catalysts Entrapment in Sol–Gel and Polysiloxane Matrices Microencapsulation and Polymer‐Incarcerated Methods Supramolecular Complexation: Mechanical Immobilization Tethered Metal Complexes Multifunctional Surfaces Spatial Restrictions Imparted by Periodic Mesoporous Silica Site Isolation via Spatial Patterning of the Silica Surface Grafted Metal Complexes: Surface Organometallic Chemistry ( SOMC ) Alkyl‐Based SOMC Alkoxide‐Based SOMC Amide‐Based SOMC Molecular Model Oxo–Surfaces Metal–Organic Assemblies: Self‐Immobilized Homogeneous Catalysts Metal–Organic Frameworks A Achiral Metal–Organic Assemblies B Chiral Metal–Organic Assemblies Matrix‐Embedded Catalysts A Sol–Gel‐Processed Interphase Catalysts B Organic–Polymer‐Embedded Catalysts C Self‐Immobilizing Polymerization Catalysts D Molecularly Imprinted Polymers Liquid Crystal Assemblies.