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Crystal structure of Tutton’s salts, Cs2[MII(H2O)6](SO4)2, MII = Mg, Mn, Fe, Co, Ni, Zn
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Abstract Cs2H12MgO14S2, monoclinic, P121/a1 (No. 14), a = 9.338(2) Å, b = 12.849(4) Å, c = 6.361(2) Å, β = 107.07(2)°, V = 729.6 Å3, Z = 2, Rgt(F) = 0.017, wRref(F2) = 0.041, T = 293 K. Cs2H12MnO14S2, monoclinic, P121/a1 (No. 14), a = 9.418(3) Å, b = 12.963(2) Å, c = 6.386(3) Å, β = 107.17(4)°, V = 744.9 Å3, Z = 2, Rgt(F) = 0.017, wRref(F2) = 0.030, T = 293 K. Cs2FeO14H12S2, monoclinic, P121/a1 (No. 14), a = 9.357(2) Å, b = 12.886(2) Å, c = 6.381(1) Å, β = 106.94(1)°, V = 736.0 Å3, Z = 2, Rgt(F) = 0.015, wRref(F2) = 0.030, T = 293 K. CoCs2H12O14S2, monoclinic, P121/a1 (No. 14), a = 9.318(1) Å, b = 12.826(3) Å, c = 6.3650(9) Å, β = 107.13(1)°, V = 727.0 Å3, Z = 2, Rgt(F) = 0.021, wRref(F2) = 0.049, T = 293 K. Cs2H12NiO14S2, monoclinic, P121/a1 (No. 14), a = 9.259(2) Å, b = 12.767(2) Å, c = 6.358(1) Å, β = 107.00(2)°, V = 718.7 Å3, Z = 2, Rgt(F) = 0.014, wRref(F2) = 0.027, T = 293 K. Cs2H12O14S2Zn, monoclinic, P121/a1 (No. 14), a = 9.314(2) Å, b = 12.817(2) Å, c = 6.369(2) Å, β = 106.94(2)°, V = 727.3 Å3, Z = 2, Rgt(F) = 0.015, wRref(F2) = 0.033, T = 293 K.
Walter de Gruyter GmbH
Title: Crystal structure of Tutton’s salts, Cs2[MII(H2O)6](SO4)2, MII = Mg, Mn, Fe, Co, Ni, Zn
Description:
Abstract Cs2H12MgO14S2, monoclinic, P121/a1 (No.
14), a = 9.
338(2) Å, b = 12.
849(4) Å, c = 6.
361(2) Å, β = 107.
07(2)°, V = 729.
6 Å3, Z = 2, Rgt(F) = 0.
017, wRref(F2) = 0.
041, T = 293 K.
Cs2H12MnO14S2, monoclinic, P121/a1 (No.
14), a = 9.
418(3) Å, b = 12.
963(2) Å, c = 6.
386(3) Å, β = 107.
17(4)°, V = 744.
9 Å3, Z = 2, Rgt(F) = 0.
017, wRref(F2) = 0.
030, T = 293 K.
Cs2FeO14H12S2, monoclinic, P121/a1 (No.
14), a = 9.
357(2) Å, b = 12.
886(2) Å, c = 6.
381(1) Å, β = 106.
94(1)°, V = 736.
0 Å3, Z = 2, Rgt(F) = 0.
015, wRref(F2) = 0.
030, T = 293 K.
CoCs2H12O14S2, monoclinic, P121/a1 (No.
14), a = 9.
318(1) Å, b = 12.
826(3) Å, c = 6.
3650(9) Å, β = 107.
13(1)°, V = 727.
0 Å3, Z = 2, Rgt(F) = 0.
021, wRref(F2) = 0.
049, T = 293 K.
Cs2H12NiO14S2, monoclinic, P121/a1 (No.
14), a = 9.
259(2) Å, b = 12.
767(2) Å, c = 6.
358(1) Å, β = 107.
00(2)°, V = 718.
7 Å3, Z = 2, Rgt(F) = 0.
014, wRref(F2) = 0.
027, T = 293 K.
Cs2H12O14S2Zn, monoclinic, P121/a1 (No.
14), a = 9.
314(2) Å, b = 12.
817(2) Å, c = 6.
369(2) Å, β = 106.
94(2)°, V = 727.
3 Å3, Z = 2, Rgt(F) = 0.
015, wRref(F2) = 0.
033, T = 293 K.
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