Effect of Long-Term Stockpiling on Oxidation and Flotation Response of Low-Grade Copper Sulphide Ore

Since the start-up of the Sossego copper concentrator, located in the Carajás Mineral Province in the southeast of Para State, Brazil, the low-grade ore (~0.34% Cu) has been stockpiled, as defined in the long-term mine plan, to be reclaimed at the end of the mine life. Given this imminent need to process around 40 Mt of this low-grade ore, questions have been raised related to the extent of oxidation that might have occurred in this stockpiled ore. In this context, a study was designed to characterize the stockpiled ore and assess the effect of the ore oxidation on its flotation response. A sampling campaign of the stockpiled ore was carried out to analyze the main variables that could influence the level of oxidation, and, consequently, copper recovery, such as stockpiling time, depth, and particle size. The results showed that there are two main factors negatively impacting the copper recovery of the low-grade stockpiled ore: the surface oxidation and the level of liberation of the copper mineral. Depth and period of stockpiling were not found to influence the level of oxidation, nor the flotation response. An empirical model was proposed for the copper recovery in the rougher stage, which resulted in a predicted value of 90.7%, which was lower than that for the fresh (and higher copper content) ore fed to the plant (93%).