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Orientation of Vanadyl Phthalocyanine Grown by Molecular Beam Epitaxy on KBr-KCl Mixed Crystals with Various Lattice Constants

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We have studied the effect of the lattice constants of substrates on the crystal orientation of films grown by molecular beam epitaxy. Vanadyl phthalocyanine films were epitaxially grown on KBr-KCl mixed crystals with continuously varying lattice constants. The unidirectional (3×3)R45° orientation and the bidirectional (√10×√10)R±27° orientation were predominant on the KBr-rich and KCl-rich substrates, respectively. We found that the orientation changes from the (3×3)R45° structure to the (√10×√10)R±27° structure at about the KCl fractions of 20 wt%.
Title: Orientation of Vanadyl Phthalocyanine Grown by Molecular Beam Epitaxy on KBr-KCl Mixed Crystals with Various Lattice Constants
Description:
We have studied the effect of the lattice constants of substrates on the crystal orientation of films grown by molecular beam epitaxy.
Vanadyl phthalocyanine films were epitaxially grown on KBr-KCl mixed crystals with continuously varying lattice constants.
The unidirectional (3×3)R45° orientation and the bidirectional (√10×√10)R±27° orientation were predominant on the KBr-rich and KCl-rich substrates, respectively.
We found that the orientation changes from the (3×3)R45° structure to the (√10×√10)R±27° structure at about the KCl fractions of 20 wt%.

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