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Synthesis and Characterization of Zirconium Metal Complexes Derived from Benzene-1, 4-dicarboxylic acid
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Amongst organo-metallic frameworks (OMFs), the metallic framework having Zirconium metal indicate fascinating structural properties and excellent stability. Such organo-metallic frameworks (OMFs) function as a potential material for practical application. Even though these particular organo-metallic frameworks are in the early developmental stage but considerable advancements have been carried out recently. We studied the characterization of zirconium-based organo-metallic frameworks. We built Zr-based OMFs by four different synthetic ways. Initially, upgraded preparation under green and commercially feasible conditions has been carried out by modifying Zr-OMFs. Zirconium based OMFs having different structures are then classified and explained based on various organic ligands and zirconium-based secondary building units. We have synthesized the zirconium metal complexes; they have been characterized on the bases of FT-IR and CHNS analyzer. FT-IR results show binding of metal with the Benzene-1, 4-dicarboxylic acid [C6H4 (COOH) 2]. Zirconium metal can bind with the organic substances for the construction of a variety of complexes. From my research work, it is concluded that zirconium metal forms a polymeric complex with terephthalic acid. In which oxygen atoms of Terephthalic acid form bridging structure with the zirconium metal. Our study based on a particular type of OMF is likely expected to present guidance for in-depth exploration of OMFs towards practical applications. It is concluded that the metal-organic frameworks (MOFs) of zirconium metal have many applications in the field of chemistry, biology and other numerous fields of science
Chemical Society of Pakistan
Title: Synthesis and Characterization of Zirconium Metal Complexes Derived from Benzene-1, 4-dicarboxylic acid
Description:
Amongst organo-metallic frameworks (OMFs), the metallic framework having Zirconium metal indicate fascinating structural properties and excellent stability.
Such organo-metallic frameworks (OMFs) function as a potential material for practical application.
Even though these particular organo-metallic frameworks are in the early developmental stage but considerable advancements have been carried out recently.
We studied the characterization of zirconium-based organo-metallic frameworks.
We built Zr-based OMFs by four different synthetic ways.
Initially, upgraded preparation under green and commercially feasible conditions has been carried out by modifying Zr-OMFs.
Zirconium based OMFs having different structures are then classified and explained based on various organic ligands and zirconium-based secondary building units.
We have synthesized the zirconium metal complexes; they have been characterized on the bases of FT-IR and CHNS analyzer.
FT-IR results show binding of metal with the Benzene-1, 4-dicarboxylic acid [C6H4 (COOH) 2].
Zirconium metal can bind with the organic substances for the construction of a variety of complexes.
From my research work, it is concluded that zirconium metal forms a polymeric complex with terephthalic acid.
In which oxygen atoms of Terephthalic acid form bridging structure with the zirconium metal.
Our study based on a particular type of OMF is likely expected to present guidance for in-depth exploration of OMFs towards practical applications.
It is concluded that the metal-organic frameworks (MOFs) of zirconium metal have many applications in the field of chemistry, biology and other numerous fields of science.
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