On the stability of CaS in liquid steel containing alumina or spinel inclusions

In secondary steelmaking, calcium treatment is practised to modify the solid alumina or spinel inclusions into liquid or partially liquid calcium aluminates. It has been seen that the dissolved calcium reacts with sulfur or oxygen present in the steel to form CaS or CaO type of transient inclusions. Post-calcium treatment these transient inclusions further react with pre-existing alumina or spinel inclusions and modify them. In addition, direct modification of pre-existing inclusions is also reported in the literature. In the present study, laboratory-scale induction furnace-based experiments are carried out to melt electrolytic iron in an alumina crucible followed by deoxidation with aluminium. The CaS-based composite material, prepared in-house, is added after the aluminium deoxidation to study the stability of CaS at the steelmaking temperature. Multiple steel samples were also taken to track the dissociation of CaS by means of sulfur pick-up in steel. Additionally, inclusion analysis of these steel samples was also performed to track changes in the chemical composition of inclusions in response to CaS addition. It has been seen that the CaS dissociates leading to a gradual pick-up of sulfur in steel. The scanning electron microscope – energy dispersive X-ray spectroscopy (SEM-EDS) analysis reveals that the alumina crucible and floated alumina inclusions are modified into calcium aluminates and the extent of modification depends on the contact time of CaS with the two sources of alumina mentioned earlier. However, the modification of alumina inclusions in the bulk steel did not occur during these experiments.