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Enantioselective Functionalization of Inert C(sp 3 )H Bonds by Photochemistry
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Abstract
The selective functionalization of inert CH bonds is regarded as one of the most attractive research field due to the advantages of expanding diversity, reducing waste and synthetic economy in modifying organic compounds. However, because of the high bond energy, similar bond strengths and steric environments, the CH bond functionalization meets the challenge of controlling the regio‐ and stereoselectivity. Due to the efficient electron transfer and energy transfer, the photocatalysis could provide an accessible alternative for the regioselective functionalization of inert CH bonds. In recent years, the enantioselective functionalization of inert CH bonds by photochemistry has been developed. This article summarized this field as photocatalysis with three main strategies: transition‐metal catalysis, chiral Lewis acid catalysis, and chiral organocatalysis.
Title: Enantioselective Functionalization of Inert C(sp
3
)H Bonds by Photochemistry
Description:
Abstract
The selective functionalization of inert CH bonds is regarded as one of the most attractive research field due to the advantages of expanding diversity, reducing waste and synthetic economy in modifying organic compounds.
However, because of the high bond energy, similar bond strengths and steric environments, the CH bond functionalization meets the challenge of controlling the regio‐ and stereoselectivity.
Due to the efficient electron transfer and energy transfer, the photocatalysis could provide an accessible alternative for the regioselective functionalization of inert CH bonds.
In recent years, the enantioselective functionalization of inert CH bonds by photochemistry has been developed.
This article summarized this field as photocatalysis with three main strategies: transition‐metal catalysis, chiral Lewis acid catalysis, and chiral organocatalysis.
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