EPR Spectroscopy in Electrochemistry

Title: EPR Spectroscopy in Electrochemistry

Description:

Abstract The sections in this article are Introduction Principles of EPR Spectroscopy EPR Theory The g ‐value Linewidths Spin‐lattice Relaxation Spin–spin Relaxation Hyperfine Structure EPR Instrumentation In Situ Electrochemical EPR : Cell Design The Bard–Goldberg Cell Cell Design Typical Applications The Allendoerfer Cells Cell Design The Coaxial Cell Application The Loop‐gap Resonator Cell Application The Channel Electrode Cell Cell Design Application The Albery In Situ Tube Electrode Cell Cell Design Application The In Situ Coaxial Flow Cell Cell Design Application The Bond In Situ Microelectrode Cell Cell Design Application The In Situ Wall‐jet Electrode Cell Cell Design Application The Dunsch–Petr–Neudeck Cell for In Situ UV ‐ VIS EPR Spectroelectro‐ chemistry Cell Design Application The Dryfe–Webster Cell for Charge Transfer Across a Liquid|Liquid Phase Boundary Cell Design Typical Applications Illustrative Examples of EPR in Electrochemistry Radical and Radical Ion Identification The Anodic Oxidation of para ‐Aminodiphenylamine ( PAD ) The Reduction of Dicyanobenzene The Reduction of C 60 Spin Trapping Electrode Reaction Kinetics and Mechanism EC Versus ECE ECE Versus DISP 1 EC ′ Comproportionation Reactions Photoelectrochemical EPR Modified Electrodes Electrochemical EPR in Ionic Liquids Conclusion Acknowledgments.