Closed-loop chemical recycling of a biobased poly(oxanorbornene-fused γ-butyrolactone)

New polymers, properly designed for end-of-life and efficiently formed from renewable carbon, are key to the transition to a more sustainable, circular plastics economy. Ring-opening polymerization (ROP) of bicyclic lactones is a promising method for the production of intrinsically recyclable polyesters, but most lactone monomers lack an efficient synthesis route from biobased starting materials, even though this is essential to sustainably account for material loss during the life cycle. Here-in, we present the exceptionally rapid and controlled polymerization of a fully biobased tricyclic oxanorbornene-fused γ-butyrolactone monomer (M1). Polyester P(M1) was formed in low dispersity (Đ = 1.2 – 1.3) and controllable molecular weight up to Mn = 76.8 kg mol−1, and exhibits a high glass transition temperature (Tg = 120 °C). The orthogonal olefin and lactone functionalities offer access to a wide range of promising materials, as showcased by post-polymerization modification by hydrogenation of the olefin, which increased polymer thermal stability by over 100 °C. Next to rapid hydrolytic degrada-tion and solvolysis, the poly(oxanorbornene-fused γ-butyrolactone) could be cleanly chemically recycled back to the mono-mer (CRM), in line with its favorable ceiling temperature (Tc) of 73 °C. The DFT-computed ΔH° of ring-opening with methanol of γ-butyrolactone-based monomers provided a model to predict Tc, and the DFT-computed and X-ray crystal struc-ture-derived structural parameters of M1, hydrogenated analogue M1-H2 and regioisomer M2 offered insights into the struc-tural descriptors that cause the high polymerizability of M1, which is key to establishing structure-property relations.