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Rongalite‐initiated addition of perfluoroalkyl iodides to olefins
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AbstractPerfluoroalkyl iodides reacted with olefins in aqueous acetonitrile in the presence of Rongalite‐sodium bicarbonate under mild conditions to give the corresponding 1:1 adducts in moderate to high yields. The formation of these products and the orientation of the addition seemed to show that radicals took part in the reaction. This provides a convenient method for perfluoroalkylation.
Title: Rongalite‐initiated addition of perfluoroalkyl iodides to olefins
Description:
AbstractPerfluoroalkyl iodides reacted with olefins in aqueous acetonitrile in the presence of Rongalite‐sodium bicarbonate under mild conditions to give the corresponding 1:1 adducts in moderate to high yields.
The formation of these products and the orientation of the addition seemed to show that radicals took part in the reaction.
This provides a convenient method for perfluoroalkylation.
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