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Thermodynamic re-assessment of the Al-Sn-Zn ternary system
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In this paper, a thermodynamic re-assessment of the Al-Sn-Zn ternary system was performed by means of the CALculation of PHAse Diagram (CALPHAD) approach. The thermodynamic descriptions of the binary Al-Sn, Al-Zn, and Sn-Zn systems from the literature were directly adopted, and the newly reported experimental phase equilibria, enthalpies of mixing, and activities of Al in the ternary liquid phase were taken into account. A set of self-consistent thermodynamic parameters for the ternary Al-Sn-Zn system were finally obtained. A comprehensive comparison between the presently calculated phase equilibria/thermodynamic properties and the experimental data indicates that the present thermodynamic descriptions of the ternary Al-Sn-Zn system show very good agreement with most of the experimental data. The further direct comparison with the calculated results due to the previous assessment demonstrates that a significant improvement was achieved by the present assessment though fewer ternary interaction parameters were utilized.
National Library of Serbia
Title: Thermodynamic re-assessment of the Al-Sn-Zn ternary system
Description:
In this paper, a thermodynamic re-assessment of the Al-Sn-Zn ternary system was performed by means of the CALculation of PHAse Diagram (CALPHAD) approach.
The thermodynamic descriptions of the binary Al-Sn, Al-Zn, and Sn-Zn systems from the literature were directly adopted, and the newly reported experimental phase equilibria, enthalpies of mixing, and activities of Al in the ternary liquid phase were taken into account.
A set of self-consistent thermodynamic parameters for the ternary Al-Sn-Zn system were finally obtained.
A comprehensive comparison between the presently calculated phase equilibria/thermodynamic properties and the experimental data indicates that the present thermodynamic descriptions of the ternary Al-Sn-Zn system show very good agreement with most of the experimental data.
The further direct comparison with the calculated results due to the previous assessment demonstrates that a significant improvement was achieved by the present assessment though fewer ternary interaction parameters were utilized.
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