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The electrically induced polymerization of 1,3,5‐trioxane
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AbstractThe electroinitiating polymerization of 1,3,5‐trioxane in solution and molten state with tetraethylammonium hexachloroantimonate has been investigated. Molecular weights of the polymers, as indicated by their viscosity numbers increase with increasing initial monomer concentration and decreasing current levels. The induction period of polymerization is dependent on the monomer concentration and reaction temperature. The overall activation energy of the polymerization was determined to be about 10,00 kcal/mol (41,83 kJ/mol). The true initiator appears to be the protonic acid formed in situ during the course of electrolysis. The polymerization of trioxane was also carried out chemically with SbCl5 and H3O⊕SbCl.
Title: The electrically induced polymerization of 1,3,5‐trioxane
Description:
AbstractThe electroinitiating polymerization of 1,3,5‐trioxane in solution and molten state with tetraethylammonium hexachloroantimonate has been investigated.
Molecular weights of the polymers, as indicated by their viscosity numbers increase with increasing initial monomer concentration and decreasing current levels.
The induction period of polymerization is dependent on the monomer concentration and reaction temperature.
The overall activation energy of the polymerization was determined to be about 10,00 kcal/mol (41,83 kJ/mol).
The true initiator appears to be the protonic acid formed in situ during the course of electrolysis.
The polymerization of trioxane was also carried out chemically with SbCl5 and H3O⊕SbCl.
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