Hydrated komatiites as a source of water for TTG formation in the Archean

Water plays a crucial role in the formation of new crust on modern Earth. Today, new continental crust is created through arc magmatism by fluid-fluxed mantle melting above subduction zones. The aqueous fluid is derived from the breakdown of hydrous phases in subducted oceanic crust as a result of a delicate interplay between phase stability and the cold thermal conditions in the slab. Hydrated and subducted ultramafic (mantle) rocks play a key role in supplying the water needed for wet mantle melting and provide an important link between the Earth’s deep water cycle and formation of crust with an average andesitic composition.Archean felsic crust consists of the typical Tonalite-Trondhjemite-Granite (TTG) Series, which were likely produced from melting of altered basaltic precursors. Previous studies suggest that the water-present partial melting of metamorphosed basalt at temperatures of 750–950 °C is required to produce large volumes of partial melt with TTG compositions. However, the source of such water is unknown and exposed serpentinised mantle rocks likely played a negligible role in the early Earth’s water cycle.We propose that hydrated komatiites played a vital role in TTG genesis. Using petrology, mineral chemistry and phase equilibria modelling of representative komatiite samples, combined with analysis of a global geochemical dataset of komatiites and basaltic komatiites, we show that during metamorphism hydrated komatiites can release at least 6 wt. % mineral-bound water. The great majority of this water is released by breakdown of chlorite and tremolite at temperatures between 680 and 800 °C. As the temperatures of komatiite dehydration are above the wet basalt solidus, the released water can trigger voluminous partial melting of basalt to ultimately create TTG batholiths. This considerable hydration potential of komatiites is due to their high XMg, which stabilises hydrous minerals during oceanic alteration on the seafloor, but also extends the stability of Mg-rich chlorite to high temperatures. During prograde metamorphism, the XMg, CaO and Al2O3 content of the reactive rock composition determines the proportion of chlorite vs amphibole, and therefore the volume of water which can be transported to temperatures of > 750 °C. Therefore, we suggest that water released from dehydrating komatiites - regardless of the prograde P–T path (i.e., tectonic scenario) they experienced - provided the free water necessary to partially melt large volumes of basalts to form the prominent and expansive TTG suits in the Archean. Even though komatiites make up moderate portions of greenstone belts, they thus likely played a key role in early crustal formation and the Earths’ early water cycle.