Recommended Critical Temperatures. Part I. Aliphatic Hydrocarbons

This work deals with the critical temperature (Tc) for saturated and unsaturated aliphatic hydrocarbons. For 175 hydrocarbons (branched alkanes, branched and unbranched alkenes, and alkynes), an existing lack of critical temperature values have been complemented. Prediction methods have been used, the usefulness of which for specific groups and subgroups of the above mentioned hydrocarbons had been previously critically evaluated. The evaluation of accuracy of the relevant aspects of these methods is given in this study. An additional result of this work is the creation of a set of recommended experimental data on critical temperatures and normal boiling points for aliphatic hydrocarbons. Such a set has been created mainly for the purpose of evaluation of prediction methods applied in this study.