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Transitions in polymer melts
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AbstractIt is shown that the liquid‐liquid transition Tll in polymer melts need not be a true polymer transition but can be an artifact of the torsional braid analysis technique. The shift in Tll with molecular weight then is due to the variation of viscosity with molecular weight.
Title: Transitions in polymer melts
Description:
AbstractIt is shown that the liquid‐liquid transition Tll in polymer melts need not be a true polymer transition but can be an artifact of the torsional braid analysis technique.
The shift in Tll with molecular weight then is due to the variation of viscosity with molecular weight.
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