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AgOAc-Catalyzed Aldehyde Allylation Using Allyldimethyl(2-pyridyl)silane
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Abstract
Silver salts having relatively strong Ag–O bond were found to promote the allylation of aldehydes with allyldimethyl(2-pyridyl)silane. Catalytic allylation is also possible when AgOAc was employed. A novel cooperative activation of allyl(2-pyridyl)silane has been implicated from several control experiments.
Oxford University Press (OUP)
Title: AgOAc-Catalyzed Aldehyde Allylation Using Allyldimethyl(2-pyridyl)silane
Description:
Abstract
Silver salts having relatively strong Ag–O bond were found to promote the allylation of aldehydes with allyldimethyl(2-pyridyl)silane.
Catalytic allylation is also possible when AgOAc was employed.
A novel cooperative activation of allyl(2-pyridyl)silane has been implicated from several control experiments.
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