Diffusion creep of a Na-Ca-amphibole-bearing blueschist

<p>Blueschists are a major constituent rock type along the subduction zone interface and therefore critical to our understanding of subduction zone dynamics. Previous experimental work on natural blueschists focus on either seismic anisotropy or on the process of eclogization of a blueschist aggregate; however, little is known about the mechanical properties of blueschist rocks. We have conducted a suite of general shear deformation experiments in the Griggs apparatus to constrain the rheology of a blueschist aggregate. The sample material derives from a natural blueschist that was crushed into a powder. The powder consists of ~55% sodic amphibole, ~30% epidote, ~8% quartz, ~5% titanite, ~2% ilmenite, and <1% mica. Deformation experiments were conducted at 1.0 GPa confining pressure, temperatures of 650, 675, 700, and 750°C, and no water added. All of the deformation experiments were strain rate stepping experiments with either 4 or 5 strain rate steps per experiment with strain rates ranging from ~2.7e-5 to 5.2e-7 s-1. Based on the mechanical data we determine a stress exponent of 1.9 +/- 0.3. Microstructural and EDS analysis shows the initial Na-amphibole grains transform into a fine-grained aggregate of new Na-Ca-amphibole with lower Na and Si and higher Fe and Ca plus albite and ilmenite. The fine-grained aggregates accommodate the majority of the strain while epidote deforms by rigid body rotation or brittle deformation. Based on both the mechanical and microstructural observations, we interpret the fine-grained aggregates to be deforming by diffusion creep. Additional analyses will be conducted to constrain the grain size to develop flow law parameters to estimate the rheology of the subduction zone interface.</p>