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Fractal Characteristics of Multi-Scale Pore Structure of Coal Measure Shales in the Wuxiang Block, Qinshui Basin

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Due to the diverse origins of shale reservoirs, the coal measure shales of the Wuxiang block, Qinshui Basin typically exhibit fractal pore structures, which significantly influence shale gas occurrence and migration. Clarifying the fractal nature of pore structures is significant for the efficient development and utilization of shale gas. In this study, mercury intrusion porosimetry and liquid nitrogen adsorption experiments were conducted to develop a method that integrates pore compressibility correction and nitrogen adsorption for pore structure characterization. On this basis, this study analyzed the fractal characteristics of coal measure shale pore structures across multiple scales. The results reveal that coal measure shale pores exhibit a three-stage fractal pattern, consisting of three regions with pore diameters >65 nm (seepage pores), 6–65 nm (transition pores), and <6 nm (micropores). Samples with fractal dimensions of seepage pores (Da) exceeding 2.9 and transition pores (D1) exceeding 2.5 tend to have larger specific surface areas and more complex pore structures; this is indicated by the increased surface roughness of large-scale pores, which hinders gas seepage. Samples with lower fractal dimension of micropores (D2)—in the range of 2.2–2.8—exhibit higher micropore development, larger specific surface area, and simpler pore structures, as demonstrated by a greater number of micropores and a more uniform pore distribution, which promotes gas adsorption.
Title: Fractal Characteristics of Multi-Scale Pore Structure of Coal Measure Shales in the Wuxiang Block, Qinshui Basin
Description:
Due to the diverse origins of shale reservoirs, the coal measure shales of the Wuxiang block, Qinshui Basin typically exhibit fractal pore structures, which significantly influence shale gas occurrence and migration.
Clarifying the fractal nature of pore structures is significant for the efficient development and utilization of shale gas.
In this study, mercury intrusion porosimetry and liquid nitrogen adsorption experiments were conducted to develop a method that integrates pore compressibility correction and nitrogen adsorption for pore structure characterization.
On this basis, this study analyzed the fractal characteristics of coal measure shale pore structures across multiple scales.
The results reveal that coal measure shale pores exhibit a three-stage fractal pattern, consisting of three regions with pore diameters >65 nm (seepage pores), 6–65 nm (transition pores), and <6 nm (micropores).
Samples with fractal dimensions of seepage pores (Da) exceeding 2.
9 and transition pores (D1) exceeding 2.
5 tend to have larger specific surface areas and more complex pore structures; this is indicated by the increased surface roughness of large-scale pores, which hinders gas seepage.
Samples with lower fractal dimension of micropores (D2)—in the range of 2.
2–2.
8—exhibit higher micropore development, larger specific surface area, and simpler pore structures, as demonstrated by a greater number of micropores and a more uniform pore distribution, which promotes gas adsorption.

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