Particularities of High Oxygen Content Biofuels Pyrolysis Process

Generating capacities supplied by solid biomass (renewable waste) gather at the moment less than 4.5% of the total renewable power installed worldwide. Given the two folded implications of such technology development and spreading (i.e. energy production and waste management), researches regarding efficient conversion processes and improved power facilities are of great interest currently. In this context, the paper addresses the particularities of high oxygen content biofuels pyrolysis, proposing innovative solutions to overcome the issues found in experimental investigations. Based on thorough experimental research conducted on agricultural wooden biomass and poultry manure, a number of problems arise. Among them, it is highlighted the heating in the absence of oxidants, an undesirable internal process caused by the high oxygen content, which contravenes the general principles regarding pyrolysis. Furthermore, the high oxygen content is associated with great moisture percentages. The present paper reveals the challenges determined by some negative aspects emerging during the pyrolysis of high oxygen content biofuels. Several solutions are proposed to improve the efficiency of the conversion process through adequate control. For instance, it is pointed out that the temperature level at which the pyrolysis process develops plays a crucial role in the general energy balance. On this matter, investigating poultry manure pyrolysis at low temperatures, a significant decrease of the final coke product is noticed. Poultry manure pyrolysis results as a suitable and simple solution to be employed for waste treatment purposes, as its combustible effects (combustible gases and semicoke / coke) are good candidates for energy production.