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TAS‐Indolid und TAS‐Carbazolid: Strukturen von [TAS]+[IndHInd]− und [TAS]+[Carb]−·½CarbH
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TAS Indolide and TAS Carbazolide: Structures of [TAS]+[IndHInd]− and [TAS]+[Carb]−·½CarbHFrom the reaction of TAS‐fluoride [(Me2N)3S]+[Me3SiF2]− with trimethylsilyl‐indole and trimethylsilyl‐carbazole TAS‐indolide and TAS‐carbazolide are formed. During crystallisation partially protonation to indole and carbazole occurs, resulting in the formation of [TAS]+[IndHInd]− (3a) and [TAS]+[Carb]−·½CarbH (5a) according to X‐ray analysis.
Title: TAS‐Indolid und TAS‐Carbazolid: Strukturen von [TAS]+[IndHInd]− und [TAS]+[Carb]−·½CarbH
Description:
TAS Indolide and TAS Carbazolide: Structures of [TAS]+[IndHInd]− and [TAS]+[Carb]−·½CarbHFrom the reaction of TAS‐fluoride [(Me2N)3S]+[Me3SiF2]− with trimethylsilyl‐indole and trimethylsilyl‐carbazole TAS‐indolide and TAS‐carbazolide are formed.
During crystallisation partially protonation to indole and carbazole occurs, resulting in the formation of [TAS]+[IndHInd]− (3a) and [TAS]+[Carb]−·½CarbH (5a) according to X‐ray analysis.
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