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Effect of (Li,Ce) doping in Aurivillius phase material Na0.25K0.25Bi2.5Nb2O9
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The effect of (Li,Ce) substitution for A site on the properties of Na0.25K0.25Bi2.5Nb2O9-based ceramics was investigated. The piezoelectric activity of Na0.25K0.25Bi2.5Nb2O9-based ceramics is significantly improved by the modification of lithium and cerium. The Curie temperature (TC) gradually increases from 668to684°C with increasing the (Li,Ce) modification. The piezoelectric coefficient d33 of the [(Na0.5K0.5)Bi]0.44(LiCe)0.03[ ]0.03Bi2Nb2O9 ceramic was found to be 28pC∕N, the highest value among the Na0.25K0.25Bi2.5Nb2O9-based ceramics and also almost 50% higher than the reported d33 values of other bismuth layer-structured ferroelectric systems (∼5–19pC∕N). The planar coupling factors kp and kt were found to be 8.0% and 23.0%, together with the high TC (∼670°C) and stable piezoelectric properties, demonstrating that the (Li,Ce) modified Na0.25K0.25Bi2.5Nb2O9-based material a promising candidate for high temperature applications.
Title: Effect of (Li,Ce) doping in Aurivillius phase material Na0.25K0.25Bi2.5Nb2O9
Description:
The effect of (Li,Ce) substitution for A site on the properties of Na0.
25K0.
25Bi2.
5Nb2O9-based ceramics was investigated.
The piezoelectric activity of Na0.
25K0.
25Bi2.
5Nb2O9-based ceramics is significantly improved by the modification of lithium and cerium.
The Curie temperature (TC) gradually increases from 668to684°C with increasing the (Li,Ce) modification.
The piezoelectric coefficient d33 of the [(Na0.
5K0.
5)Bi]0.
44(LiCe)0.
03[ ]0.
03Bi2Nb2O9 ceramic was found to be 28pC∕N, the highest value among the Na0.
25K0.
25Bi2.
5Nb2O9-based ceramics and also almost 50% higher than the reported d33 values of other bismuth layer-structured ferroelectric systems (∼5–19pC∕N).
The planar coupling factors kp and kt were found to be 8.
0% and 23.
0%, together with the high TC (∼670°C) and stable piezoelectric properties, demonstrating that the (Li,Ce) modified Na0.
25K0.
25Bi2.
5Nb2O9-based material a promising candidate for high temperature applications.
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