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Synthesis and Structural Characterization of Polymeric Silver(I) Butyl Xanthate
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Polymeric silver(I) butyl xanthate, [Ag(Bu-XA)]n, was synthesized and crystallographically characterized. The polymer shows chair conformation of eight-membered ring units and a novel mode of coordination, with a structural arrangement different from that in silver dialkyldithiocarbamate and dialkyldithiophosphates. The polymeric structure of the new complex is formed by corrugated planes.
Institute of Organic Chemistry & Biochemistry
Title: Synthesis and Structural Characterization of Polymeric Silver(I) Butyl Xanthate
Description:
Polymeric silver(I) butyl xanthate, [Ag(Bu-XA)]n, was synthesized and crystallographically characterized.
The polymer shows chair conformation of eight-membered ring units and a novel mode of coordination, with a structural arrangement different from that in silver dialkyldithiocarbamate and dialkyldithiophosphates.
The polymeric structure of the new complex is formed by corrugated planes.
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