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Infrared absorption study of hydrogen incorporation in thick nanocrystalline diamond films

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We present an infrared (IR) optical absorbance study of hydrogen incorporation in nanocrystalline diamond films. The thick nanocrystalline diamond films were synthesized by microwave plasma-assisted chemical vapor deposition and a high growth rate about 3.0μm∕h was achieved. The morphology, phase quality, and hydrogen incorporation were assessed by means of scanning electron microscopy, Raman spectroscopy, and Fourier-transform infrared spectroscopy (FTIR). Large amount of hydrogen bonded to nanocrystalline diamond is clearly evidenced by the huge CH stretching band in the FTIR spectrum. The mechanism of hydrogen incorporation is discussed in light of the growth mechanism of nanocrystalline diamond. This suggests the potential of nanocrystalline diamond for IR electro-optical device applications.
Title: Infrared absorption study of hydrogen incorporation in thick nanocrystalline diamond films
Description:
We present an infrared (IR) optical absorbance study of hydrogen incorporation in nanocrystalline diamond films.
The thick nanocrystalline diamond films were synthesized by microwave plasma-assisted chemical vapor deposition and a high growth rate about 3.
0μm∕h was achieved.
The morphology, phase quality, and hydrogen incorporation were assessed by means of scanning electron microscopy, Raman spectroscopy, and Fourier-transform infrared spectroscopy (FTIR).
Large amount of hydrogen bonded to nanocrystalline diamond is clearly evidenced by the huge CH stretching band in the FTIR spectrum.
The mechanism of hydrogen incorporation is discussed in light of the growth mechanism of nanocrystalline diamond.
This suggests the potential of nanocrystalline diamond for IR electro-optical device applications.

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