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Neuartige Bor‐Phosphor‐Verbindungen

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AbstractBCl3 oder C6H5BCl2 reagieren unter HCl‐Abspaltung mit SPF2NH2 oder P3N3F5NH2 zu den Verbindungen (P3N3F5NH)3B (1), (SPF2NH)3B (2) und (SPF2NH)2BC6H5 (3). Aufgrund der Massenspektren sind die Verbindungen in der Gasphase monomer. Es sind farblose Festkörper, die extrem hydrolyseempfindlich sind. Massenspektren, IR‐ und NMR‐Daten werden mitgeteilt und diskutiert.
Title: Neuartige Bor‐Phosphor‐Verbindungen
Description:
AbstractBCl3 oder C6H5BCl2 reagieren unter HCl‐Abspaltung mit SPF2NH2 oder P3N3F5NH2 zu den Verbindungen (P3N3F5NH)3B (1), (SPF2NH)3B (2) und (SPF2NH)2BC6H5 (3).
Aufgrund der Massenspektren sind die Verbindungen in der Gasphase monomer.
Es sind farblose Festkörper, die extrem hydrolyseempfindlich sind.
Massenspektren, IR‐ und NMR‐Daten werden mitgeteilt und diskutiert.

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