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LOW-TEMPERATURE EQUATION OF STATE OF SOLID METHANE
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The theoretical equation of state for solid methane, developed within the framework of perturbation theory, with the crystal consisting of spherical molecules as zero-order approximation, and octupole – octupole interaction of methane molecules as a perturbation, is proposed. Thermodynamic functions are computed on the sublimation line up to the triple point. The contribution of the octupole – octupole interaction to the thermodynamic properties of solid methane is estimated.
Odesa National University of Technology
Title: LOW-TEMPERATURE EQUATION OF STATE OF SOLID METHANE
Description:
The theoretical equation of state for solid methane, developed within the framework of perturbation theory, with the crystal consisting of spherical molecules as zero-order approximation, and octupole – octupole interaction of methane molecules as a perturbation, is proposed.
Thermodynamic functions are computed on the sublimation line up to the triple point.
The contribution of the octupole – octupole interaction to the thermodynamic properties of solid methane is estimated.
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