Search engine for discovering works of Art, research articles, and books related to Art and Culture
Javascript must be enabled to continue!
An Overview of Julia-lythgoe Olefination
View through CrossRef
Abstract:
Julia-Lythgoe olefination (or simply Julia olefination) is an olefination process between phenyl sulfones and aldehydes (or ketones) to give alkenes after alcohol functionalization and re-ductive elimination using sodium amalgam or SmI2. It is mainly used to synthesize E-alkenes and is a key step in numerous total syntheses of many natural products. This review exclusively deals with the Julia-Lythgoe olefination and concentrates mainly on the applications of this reaction in natural product synthesis covering literature up to 2021.
Bentham Science Publishers Ltd.
Title: An Overview of Julia-lythgoe Olefination
Description:
Abstract:
Julia-Lythgoe olefination (or simply Julia olefination) is an olefination process between phenyl sulfones and aldehydes (or ketones) to give alkenes after alcohol functionalization and re-ductive elimination using sodium amalgam or SmI2.
It is mainly used to synthesize E-alkenes and is a key step in numerous total syntheses of many natural products.
This review exclusively deals with the Julia-Lythgoe olefination and concentrates mainly on the applications of this reaction in natural product synthesis covering literature up to 2021.
Related Results
Julia Olefination
Julia Olefination
AbstractThe multistep preparation of trans‐olefins involving the addition of phenylsulfonyl carbanion to aldehydes or ketones to form β‐hydroxysulfones, followed by the esterificat...
Transition-Metal-Free and Selective Deconstructive Carbonyl Olefination of α-Hydroxy Ketones: A Complementary Approach to Knoevenagel Reaction
Transition-Metal-Free and Selective Deconstructive Carbonyl Olefination of α-Hydroxy Ketones: A Complementary Approach to Knoevenagel Reaction
AbstractWhile the carbonyl olefination has been extensively studied and well documented, use of α-hydroxy ketones as precursors for the carbonyl olefination is not reported, till d...
Takai Olefination
Takai Olefination
AbstractThis reaction is a coupling between aldehydes and geminal dihaloalkanes to form olefins in the presence of chromous chloride and is generally known as the Takai olefination...
Júlia Lopes de Almeida (1862-1934): uma mulher fora de seu tempo?
Júlia Lopes de Almeida (1862-1934): uma mulher fora de seu tempo?
Resumo: Este artigo tem como objetivo central refletirsobre os possíveis significados da presença feminina narede de sociabilidades que caracterizou o cenárioliterário e político d...
Sulfoxide‐Modified Julia—Lythgoe Olefination: Highly Stereoselective Di‐, Tri‐, and Tetrasubstituted Double Bond Formation.
Sulfoxide‐Modified Julia—Lythgoe Olefination: Highly Stereoselective Di‐, Tri‐, and Tetrasubstituted Double Bond Formation.
AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, ...
Las emperatrices sirias las excepcionales series monetales de Julia Domna y Julia Mamea = The «Sirian Empresses» and the Exceptional Issues of Julia Domna and Julia Mamea
Las emperatrices sirias las excepcionales series monetales de Julia Domna y Julia Mamea = The «Sirian Empresses» and the Exceptional Issues of Julia Domna and Julia Mamea
En el presente trabajo se analizan unas excepcionales series monetales acuñadas a finales del siglo II y principios del III d.C., a nombre dos de las «emperatrices sirias» que más ...
Julia Lee – Ukrainian Princess of Korea
Julia Lee – Ukrainian Princess of Korea
The article “Julia Lee – Ukrainian Princess of Korea” is researching largely unknown historical page of marriage between Yi Gu, the last crown prince of Korean royal Choseon dynast...
El munus en honor de Julia organizado por César: ritual funerario, desigualdad social y propaganda política en la Roma republicana = The munus in honour of Julia organized by Caesar: funerary ritual, social inequality and political interest in the republi
El munus en honor de Julia organizado por César: ritual funerario, desigualdad social y propaganda política en la Roma republicana = The munus in honour of Julia organized by Caesar: funerary ritual, social inequality and political interest in the republi
Resumen: Este trabajo se centra en el munus de Julia ofrecido por su padre César, para ello se analiza la figura de Julia, como hija de César y esposa de Pompeyo, y el significado ...