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An Overview of Julia-lythgoe Olefination
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Abstract:
Julia-Lythgoe olefination (or simply Julia olefination) is an olefination process between phenyl sulfones and aldehydes (or ketones) to give alkenes after alcohol functionalization and re-ductive elimination using sodium amalgam or SmI2. It is mainly used to synthesize E-alkenes and is a key step in numerous total syntheses of many natural products. This review exclusively deals with the Julia-Lythgoe olefination and concentrates mainly on the applications of this reaction in natural product synthesis covering literature up to 2021.
Bentham Science Publishers Ltd.
Title: An Overview of Julia-lythgoe Olefination
Description:
Abstract:
Julia-Lythgoe olefination (or simply Julia olefination) is an olefination process between phenyl sulfones and aldehydes (or ketones) to give alkenes after alcohol functionalization and re-ductive elimination using sodium amalgam or SmI2.
It is mainly used to synthesize E-alkenes and is a key step in numerous total syntheses of many natural products.
This review exclusively deals with the Julia-Lythgoe olefination and concentrates mainly on the applications of this reaction in natural product synthesis covering literature up to 2021.
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