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Decarbonylation Catalysis
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Abstract
Aldehydes or acid chlorides can be decarbonylated to alkanes or alkenes respectively by rhodium complexes. However, α,ω‐alkenals frequently isomerize to cyclic ketones. Palladium complexes decarbonylate aroyl cyanides. Stoichiometric reactions occur with many carbonyl compounds at low temperatures. Above 150°C, several of the reactions are catalytic. Aldehyde tautomers such as allylic alcohols or carbohydrates are also decarbonylated.
Title: Decarbonylation Catalysis
Description:
Abstract
Aldehydes or acid chlorides can be decarbonylated to alkanes or alkenes respectively by rhodium complexes.
However, α,ω‐alkenals frequently isomerize to cyclic ketones.
Palladium complexes decarbonylate aroyl cyanides.
Stoichiometric reactions occur with many carbonyl compounds at low temperatures.
Above 150°C, several of the reactions are catalytic.
Aldehyde tautomers such as allylic alcohols or carbohydrates are also decarbonylated.
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