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Oxidative Kupplung von racemischem und von optisch aktivem 3,6‐Di‐tert‐butylocta‐1,4,7‐triin‐3,6‐diol
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Ein optisch inaktives cyclisches Dimer 1 bzw. ein optisch aktives Polymer 2, das sind die Produkte der beiden Titelreaktionen. Dieser drastische Unterschied im Reaktionsverhalten ist im Hinblick auf die Bildung natürlicher, optisch aktiver Polymere von großer Bedeutung. magnified image
Title: Oxidative Kupplung von racemischem und von optisch aktivem 3,6‐Di‐tert‐butylocta‐1,4,7‐triin‐3,6‐diol
Description:
Ein optisch inaktives cyclisches Dimer 1 bzw.
ein optisch aktives Polymer 2, das sind die Produkte der beiden Titelreaktionen.
Dieser drastische Unterschied im Reaktionsverhalten ist im Hinblick auf die Bildung natürlicher, optisch aktiver Polymere von großer Bedeutung.
magnified image.
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