Modeling the Impact of Urban and Industrial Pollution on the Quality of Surface Water in Intermittent Rivers in a Semi-Arid Mediterranean Climate

Ensuring the protection of the aquatic environment and addressing the water scarcity and degradation of water quality in the Mediterranean region pose significant challenges. This study specifically aims to assess the impact of urban and industrial pollution on the ZAT River water quality. The study exploits a combination of field measurements and mathematical simulations using the PEGASE model. The objective is to evaluate how water quality changes throughout the different seasons and to determine whether olive oil factories discharge industrial wastewater into the river. The study reveals that the river water quality remains relatively stable along its course, up to km 64 in winter and km 71.77 in summer, where poor water quality is recorded. This degradation can be attributed to multiple factors. One of these factors is the discharge of industrial wastewater, which accounts for 47% of the COD pollution load. This industrial wastewater is released into the river without treatment during the production period (January–February) and inactivity period (March–May). The combined impact of urban and industrial wastewater is also associated with the decrease in water flow resulting from water withdrawals due to irrigation canals and groundwater recharge, which both contribute to the observed changes in river water quality. Importantly, field measurements combined with results obtained from the calibrated model provide compelling evidence of unauthorized wastewater discharges from the olive oil factories into the river. These results emphasize the need for stricter regulation, such as developing water quality monitoring strategies based on the use of modeling methodologies. They also emphasize the importance of improving wastewater management practices, such as setting up treatment plants for different sources of pollution or developing a co-treatment plant to mitigate the adverse impact of industrial pollution on river water quality.