Search engine for discovering works of Art, research articles, and books related to Art and Culture
ShareThis
Javascript must be enabled to continue!

Chirality and chemical processes: A few afterthoughts

View through CrossRef
AbstractChirality and chiral have become terms that pervade a wide range of disciplines in physical and life sciences. Although such terms are precisely defined, their use often engenders confusion and ambiguity. Perhaps, the most improper use of chirality, yet widely accepted, is related to its association with stereodynamics and physico‐chemical transformations, such as chiral discrimination, chiral resolution, chiral recognition, chiral synthesis, and so on. Even though this conceptual perversion has been highlighted by renowned stereochemists, it has become a recurring keyword and a hot message in modern literature. It is timely to renew the correct use and context in forums such as the present journal, adding further reflections that may help both beginners and practitioners. This short article is not intended to criticize or highlight errors, but rather to encourage a level of rigor and the use of statements, which should be universally correct. Chirality, 2007. © 2007 Wiley‐Liss, Inc.
Title: Chirality and chemical processes: A few afterthoughts
Description:
AbstractChirality and chiral have become terms that pervade a wide range of disciplines in physical and life sciences.
Although such terms are precisely defined, their use often engenders confusion and ambiguity.
Perhaps, the most improper use of chirality, yet widely accepted, is related to its association with stereodynamics and physico‐chemical transformations, such as chiral discrimination, chiral resolution, chiral recognition, chiral synthesis, and so on.
Even though this conceptual perversion has been highlighted by renowned stereochemists, it has become a recurring keyword and a hot message in modern literature.
It is timely to renew the correct use and context in forums such as the present journal, adding further reflections that may help both beginners and practitioners.
This short article is not intended to criticize or highlight errors, but rather to encourage a level of rigor and the use of statements, which should be universally correct.
Chirality, 2007.
© 2007 Wiley‐Liss, Inc.

Related Results

Molecular chirality quantification: Tools and benchmarks
Molecular chirality quantification: Tools and benchmarks
Molecular chirality has traditionally been viewed as a binary property where a molecule is classified as either chiral or achiral, yet in recent decades, mathematical methods for q...
Advances in Chirality Sensing with Macrocyclic Molecules
Advances in Chirality Sensing with Macrocyclic Molecules
The construction of chemical sensors that can distinguish molecular chirality has attracted increasing attention in recent years due to the significance of chiral organic molecules...
Chirality and Chiroptical Properties of Amyloid Fibrils
Chirality and Chiroptical Properties of Amyloid Fibrils
ABSTRACTChirality of amyloid fibrils‐linear beta‐sheet‐rich aggregates of misfolded protein chains‐often manifests in morphological traits such as helical twist visible in atomic f...
A web site for calculating the degree of chirality
A web site for calculating the degree of chirality
AbstractThe web site, http://www.csm.huji.ac.il/, uses the Continuous Chirality Measure to evaluate quantitatively the degree of chirality of a molecule, a structure, a fragment. T...
Chiral vibrational modes in small molecules
Chiral vibrational modes in small molecules
The development of quantitative methods for characterizing molecular chirality can provide an important tool for studying chirality-induced phenomena in molecular systems. Signific...
Geometrical approach to central molecular chirality: A chirality selection rule
Geometrical approach to central molecular chirality: A chirality selection rule
AbstractChirality is of primary importance in many areas of chemistry and has been extensively investigated since its discovery. We introduce here a description of central chiralit...
Nonhanded chirality in octahedral metal complexes
Nonhanded chirality in octahedral metal complexes
AbstractChiral molecules can either be handed (i.e., “shoes”) or nonhanded (“potatoes”). The only chiral ligand partition for tetrahedral metal complexes (or for a tetrahedral carb...
Chirality: A Relational Geometric‐Physical Property
Chirality: A Relational Geometric‐Physical Property
ABSTRACTThe definition of the term chirality by Lord Kelvin in 1893 and 1904 is analyzed by taking crystallography at that time into account. This shows clearly that chirality is a...

Back to Top