Javascript must be enabled to continue!
Copper-catalyzed enantioselective aziridination of styrenes
View through CrossRef
Studies regarding the copper-catalyzed enantioselective aziridination of styrenes with N-tosyloxycarbamates are presented. Catalyst, ligand, and reagent optimization will be discussed. Chiral aziridines were obtained in good yields and modest-to-good levels of stereochemical induction.
Title: Copper-catalyzed enantioselective aziridination of styrenes
Description:
Studies regarding the copper-catalyzed enantioselective aziridination of styrenes with N-tosyloxycarbamates are presented.
Catalyst, ligand, and reagent optimization will be discussed.
Chiral aziridines were obtained in good yields and modest-to-good levels of stereochemical induction.
Related Results
Aziridination
Aziridination
AbstractAziridines, smallest three‐membered nitrogen‐containing heterocycles, are important subunits of several natural products. They also function efficiently as removable chiral...
Challenging Atroposelective C–H Arylation
Challenging Atroposelective C–H Arylation
AbstractAtropisomeric molecules are privileged scaffolds, not only as ligands for asymmetric synthesis, but also as biologically active products and advanced materials. Although ve...
Palladium‐Catalyzed Enantioselective Thiocarbonylation of Styrenes
Palladium‐Catalyzed Enantioselective Thiocarbonylation of Styrenes
AbstractA highly enantioselective thiocarbonylation of styrenes with CO and thiols has been achieved by Pd catalysis, providing highly enantioenriched thioesters in good to excelle...
Palladium‐Catalyzed Enantioselective Thiocarbonylation of Styrenes
Palladium‐Catalyzed Enantioselective Thiocarbonylation of Styrenes
AbstractA highly enantioselective thiocarbonylation of styrenes with CO and thiols has been achieved by Pd catalysis, providing highly enantioenriched thioesters in good to excelle...
Ascorbate Oxidase
Ascorbate Oxidase
Abstract
Ascorbate oxidase (AO) is a multicopper oxidase related to laccase and ceruloplasmin. It catalyzes the four‐electron reduction of dioxygen to water ...
Ascorbate Oxidase
Ascorbate Oxidase
Abstract
Ascorbate oxidase (AO) is a multicopper oxidase related to laccase and ceruloplasmin. It catalyzes the four‐electron reduction of dioxygen to water ...
Transition-Metal-Catalyzed Direct Arylation of Ammonia
Transition-Metal-Catalyzed Direct Arylation of Ammonia
AbstractIn the past few decades, transition-metal-catalyzed direct amination of aryl halides with ammonia has attracted significant attention from chemists because of its broad sub...
Aziridination via Nitrogen-Atom Transfer to Olefins from Photoexcited Azoxy-Triazenes
Aziridination via Nitrogen-Atom Transfer to Olefins from Photoexcited Azoxy-Triazenes
Herein, we report that readily accessible azoxy-triazenes can serve as nitrogen atom sources under visible-light excitation for the efficient aziridination of alkenes. This approac...

