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ChemInform Abstract: THIADIAZEPINE UND INTERMEDIAERE SULFIDE

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AbstractNach der Technik von Tafel und Mauritz werden aus den w‐Halogenketonen (I) mit NaZS die Sulfide (II) (50%Ausbeute) erhalten, von denen (IIa)‐(IId) mit Hydrazinhydrat bei 80°C zu den Thiadiazepinen (IIIa)‐(IIId) cyclisieren.
Title: ChemInform Abstract: THIADIAZEPINE UND INTERMEDIAERE SULFIDE
Description:
AbstractNach der Technik von Tafel und Mauritz werden aus den w‐Halogenketonen (I) mit NaZS die Sulfide (II) (50%Ausbeute) erhalten, von denen (IIa)‐(IId) mit Hydrazinhydrat bei 80°C zu den Thiadiazepinen (IIIa)‐(IIId) cyclisieren.

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