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Heck–Mizoroki coupling of vinyliodide and applications in the synthesis of dienes and trienes
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Vinyliodide reacts chemoselectively under Heck–Mizoroki conditions with terminal alkenes to give diene products, including vinyl boronate esters, and the resulting dienylboronate undergoes Suzuki–Miyaura coupling with aryl, heteroaryl and alkenyl halides to access dienes and trienes.
Royal Society of Chemistry (RSC)
Title: Heck–Mizoroki coupling of vinyliodide and applications in the synthesis of dienes and trienes
Description:
Vinyliodide reacts chemoselectively under Heck–Mizoroki conditions with terminal alkenes to give diene products, including vinyl boronate esters, and the resulting dienylboronate undergoes Suzuki–Miyaura coupling with aryl, heteroaryl and alkenyl halides to access dienes and trienes.
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