Effects of Surfactant Compounding on the Wettability Characteristics of Zhaozhuang Coal: Experiment and Molecular Simulation

Abstract It is important to study the mechanism of wettability of Zhaozhuang coal with surfactant compoundings in order to prevent dust disaster in the process of coal seam mining. By means of molecular simulation, the amounts of water absorbed by different systems, which are composed of monomer surfactant molecules and Zhaozhuang coal molecules or compounding surfactant molecules and Zhaozhuang coal molecules, were compared in this paper. The simulation results show that the system composed of 0.2% sodium dodecyl benzene sulfonate (SDBS) and 0.3% alcohol polyoxyethylene ether (AEO3) had the maximum water absorption amount of 479, which is significantly better than that of other compounding methods and of each monosurfactant system. Analysis results show that the interference of non-ionic surfactant can greatly reduce the electrostatic repulsion between ionic surfactants and make the adsorption sites on the Zhaozhuang coal molecule more compact. The experimental results show that the decreasing percentage of the contact angle of this type of compounding solution on Zhaozhuang coal was 83.74%, which is the best of the six compounding methods. It has a high degree of consistency with the simulation results, and the molecular simulation method applied in this paper shows that it is convenient and accurate. This research plays a guiding role in dustproof work in Zhaozhuang coal mining.