Birch-bark suberin-reconstructed polyester film as packaging materials

Fossil-based polymers dominate the packaging industry thanks to their performance and low cost. However, their negative impact on our biosphere demands a paradigm shift in the industry. Nature may provide an alternative in the form of suberin. Suberin is an amorphous polyester present in plants where it contributes to controlling the water and gas exchange with the environment. The bark is rich in suberin and it represents a large by-product of the forestry industry, hence, it is a potential source of renewable monomers for the synthesis of packaging materials. In this study, we demonstrated that un-refined suberin monomers, extracted from birch bark, could be exploited to synthesize a cross-linked polyester film through a standard melt-polycondensation and compression molding process. The polyester film resulted in being translucent while blocking UV radiation, and to have an elastomer-like behavior. The measured water vapor transmission rate was comparable to other polyesters, such as polylactide and polycaprolactone. Finally, the thermal gravimetric analysis showed the lack of any unreacted suberin monomers, suggesting food packaging as a potential application, where migration of monomers must be prevented.